Crystalline morphology of poly(L-lactic acid) thin films
文献类型：期刊论文
| 作者 | Li HD ; Nie W ; Deng C ; Chen XS ; Ji XL |
| 刊名 | european polymer journal
 |
| 出版日期 | 2009 |
| 卷号 | 45期号:1页码:123-130 |
| 关键词 | POLYMER CRYSTALLIZATION QUASI-2 DIMENSIONS DIBLOCK COPOLYMER MELTING BEHAVIOR BLOCK-COPOLYMERS THERMAL-BEHAVIOR LACTIC-ACID SURFACE KINETICS GROWTH |
| ISSN号 | 0014-3057 |
| 通讯作者 | chen xs |
| 中文摘要 | crystalline morphologies of spin-coated poly(l-lactic acid) (plla) thin films under different conditions are investigated mainly with atomic force microscopy (afm) technique. when plla concentration in chloroform is varied from 0.01 to 1% gradually, disordered structure, rod-shape and larger spheres aggregates are observed in thin films subsequently. under different annealing temperature, such as at 78, 102, 122 degrees c, respectively, we can find most rod-like crystalline aggregates. interestingly, we observed that nucleation sites locate at the edge of the holes at the original crystalline stage. then, these holes developed to form chrysanthemum-like and rods subsequently with annealing time meanwhile the size and the shape of crystalline aggregate are changed. in addition. effect of substrate and solvent on morphology is also discussed. on the other hand, the possible mechanism of crystalline morphology evolution is proposed. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000263211400014 |
| 公开日期 | 2010-06-18 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/13055]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li HD,Nie W,Deng C,et al. Crystalline morphology of poly(L-lactic acid) thin films[J]. european polymer journal,2009,45(1):123-130. |
| APA | Li HD,Nie W,Deng C,Chen XS,&Ji XL.(2009).Crystalline morphology of poly(L-lactic acid) thin films.european polymer journal,45(1),123-130. |
| MLA | Li HD,et al."Crystalline morphology of poly(L-lactic acid) thin films".european polymer journal 45.1(2009):123-130. |
入库方式： OAI收割
来源：长春应用化学研究所
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