Enhanced electrochemiluminescence sensor from tris(2,2 '-bipyridyl) ruthenium(II) incorporated into MCM-41 and an ionic liquid-based carbon paste electrode
文献类型：期刊论文
| 作者 | Li J ; Huang MH ; Liu XQ ; Wei H ; Xu YH ; Xu GB ; Wang EK |
| 刊名 | analyst
 |
| 出版日期 | 2007 |
| 卷号 | 132期号:7页码:687-691 |
| 关键词 | ELECTROGENERATED CHEMI-LUMINESCENCE COMPOSITE FILMS CHEMILUMINESCENCE SURFACE SILICA NAFION RU(BPY)(3)(2+) NANOPARTICLES ECL OXALATE |
| ISSN号 | 0003-2654 |
| 通讯作者 | wang ek |
| 中文摘要 | the electrochemiluminescence (ecl) of tris(2,29-bipyridyl) ruthenium(ii) [ru(bpy)(3)(2+)] ion-exchanged in the sulfonic-functionalized mcm-41 silicas was developed with tripropylamine (tpra) as a co-reactant in a carbon paste electrode (cpe) using a room temperature ionic liquid (il) as a binder. the sulfonic-functionalized silicas mcm-41 were used for preparing an ecl sensor by the electrostatic interactions between ru( bpy)(3)(2+) cations and sulfonic acid groups. we used the il as a binder to construct the cpe (il-cpe) to replace the traditional binder of the cpe (t-cpe)-silicone oil. the results indicated that the mcm-41-modified il-cpe had more open structures to allow faster diffusion of ru( bpy)(3)(2+) and that the ionic liquid also acted as a conducting bridge to connect tpra with ru( bpy)(3)(2+) sites immobilized in the electrode, resulting in a higher ecl intensity compared with the mcm-41-modified t-cpe. herein, the detection limit for tpra of the mcm-41-modified il-cpe was 7.2 nm, which was two orders of magnitude lower than that observed at the t-cpe. when this new sensor was used in flow injection analysis (fia), the mcm-41-modified il-cpe ecl sensor also showed good reproducibility. furthermore, the sensor could also be renewed easily by mechanical polishing whenever needed. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000247526600023 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/13133]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li J,Huang MH,Liu XQ,et al. Enhanced electrochemiluminescence sensor from tris(2,2 '-bipyridyl) ruthenium(II) incorporated into MCM-41 and an ionic liquid-based carbon paste electrode[J]. analyst,2007,132(7):687-691. |
| APA | Li J.,Huang MH.,Liu XQ.,Wei H.,Xu YH.,...&Wang EK.(2007).Enhanced electrochemiluminescence sensor from tris(2,2 '-bipyridyl) ruthenium(II) incorporated into MCM-41 and an ionic liquid-based carbon paste electrode.analyst,132(7),687-691. |
| MLA | Li J,et al."Enhanced electrochemiluminescence sensor from tris(2,2 '-bipyridyl) ruthenium(II) incorporated into MCM-41 and an ionic liquid-based carbon paste electrode".analyst 132.7(2007):687-691. |
入库方式： OAI收割
来源：长春应用化学研究所
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