Highly efficient electrochemiluminescence of functionalized tris(2,2 '-bipyridyl)ruthenium(II) enrichment of its co-reactants
文献类型：期刊论文
| 作者 | Xu YH ; Gao Y ; Li T ; Du Y ; Li J ; Wang EK |
| 刊名 | advanced functional materials
 |
| 出版日期 | 2007 |
| 卷号 | 17期号:6页码:1003-1009 |
| 关键词 | TEMPERATURE IONIC LIQUIDS ELECTROGENERATED CHEMILUMINESCENCE ELECTROCHEMICAL APPLICATIONS PHYSICAL-PROPERTIES EMISSION INTENSITY CHEMICAL-ANALYSIS ORGANIC-SOLVENTS GREEN SOLVENTS LIGHT-EMISSION MOLTEN-SALTS |
| ISSN号 | 1616-301x |
| 通讯作者 | wang ek |
| 中文摘要 | an enhanced electrochemiluminescence (ecl) efficiency is obtained from the ruthenium complex tris(2,2'-bipyridyl)ruthenium(ii) (ru(bpy)(3)(2+)) by introduction of an ionic liquid (il) 1-butyl-3-methylimidazolium tetrafluoroborate (bmimbf(4)). upon addition of 1% (v/v) bmimbf(4) to 0.1 mm ru(bpy)(3)(2+) solution, a maximum increase in ecl intensity is obtained both at an indium tin oxide (ito) electrode (15-fold) and at a glassy carbon (gc) electrode (5- to 64old). furthermore, upon addition of 1% (v/v) bmimbf4 to 5 pm ru(bpy)(3)(2+)/100 mm co-reactant systems at a gc electrode, il adsorption occurs at the electrode surface, which results in a change of the polarity of the electrode surface. such functionalization greatly improves the functions of both ru(bpy)(3)(2+) and ionic liquids, as is demonstrated in the sensitive and selective concentration enrichment of the ru(bpy)(3)(2+) co-reactants. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000246414100020 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/13161]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xu YH,Gao Y,Li T,et al. Highly efficient electrochemiluminescence of functionalized tris(2,2 '-bipyridyl)ruthenium(II) enrichment of its co-reactants[J]. advanced functional materials,2007,17(6):1003-1009. |
| APA | Xu YH,Gao Y,Li T,Du Y,Li J,&Wang EK.(2007).Highly efficient electrochemiluminescence of functionalized tris(2,2 '-bipyridyl)ruthenium(II) enrichment of its co-reactants.advanced functional materials,17(6),1003-1009. |
| MLA | Xu YH,et al."Highly efficient electrochemiluminescence of functionalized tris(2,2 '-bipyridyl)ruthenium(II) enrichment of its co-reactants".advanced functional materials 17.6(2007):1003-1009. |
入库方式： OAI收割
来源：长春应用化学研究所
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