Influence of montmorillonite on syndiotactic polymerization behavior of styrene
文献类型：期刊论文
| 作者 | Yang F ; Zhang XQ ; Zhao HC ; Dong WM ; Huang BT |
| 刊名 | journal of applied polymer science
 |
| 出版日期 | 2007 |
| 卷号 | 104期号:5页码:2755-2759 |
| 关键词 | SYNDIOSPECIFIC POLYMERIZATION ETHYLENE POLYMERIZATION CATALYSTS |
| ISSN号 | 0021-8995 |
| 通讯作者 | yang f |
| 中文摘要 | the influence of montmorillonite (mmt) on the syndiotactic polymerization behavior of styrene was studied. to avoid the hydrophilic surface of the mmt coming into contact with the catalyst, which could poison it, san was introduced between the mmt and cp*ti (och3)(3). mmt was introduced into the catalytic system as a supporter for the ti catalyst (supported catalytic system) or just dispersed in the polymerization solvent directly (in situ polymerization system). the polymerization results showed that surface modification of mmt dramatically affected the catalytic activity as well as the syndiotacticity of the polymers. this is mainly explained by the insulator san preventing the formation of the inactive/little active species si-o-ti and other atactic active species resulting from the reaction of the -oh on the mmt layer surface with cp*ti(och3)(3). |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000245724100001 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/13245]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yang F,Zhang XQ,Zhao HC,et al. Influence of montmorillonite on syndiotactic polymerization behavior of styrene[J]. journal of applied polymer science,2007,104(5):2755-2759. |
| APA | Yang F,Zhang XQ,Zhao HC,Dong WM,&Huang BT.(2007).Influence of montmorillonite on syndiotactic polymerization behavior of styrene.journal of applied polymer science,104(5),2755-2759. |
| MLA | Yang F,et al."Influence of montmorillonite on syndiotactic polymerization behavior of styrene".journal of applied polymer science 104.5(2007):2755-2759. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。