Hydrogen bond-assisted crystallization: structure, growth and characterization of a new mixed-anion transition metal fluoride Na3NH4(TiF6)(SO4)center dot H2O
文献类型：期刊论文
| 作者 | Xu, DD (Xu, Dongdong); Zhang, FF (Zhang, Fangfang) ; Sun, YZ (Sun, Yanzhou); Yang, ZH (Yang, Zhihua); Dong, XY (Dong, Xiaoyu); Pan, SL (Pan, Shilie)
|
| 刊名 | NEW JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2016 |
| 卷号 | 40期号:9页码:7407-7413 |
| 通讯作者 | Zhang, FF ; Pan, SL |
| 英文摘要 | The first mixed-anion transition metal (TM) fluoride with a [MF6](x-) (M = TM cation) anion group, Na3NH4(TiF6)-(SO4)center dot H2O (NTS), was synthesized by a facile hydrothermal method. The structure of NTS features hydrogen-bonded layers constructed by four kinds of building blocks, i.e., [NH4](+), [TiF6](2-), [SO4](2-), and H2O, and four categories of hydrogen bonds, i. e., N-H center dot center dot center dot O, N-H center dot center dot center dot F, O-H center dot center dot center dot O and O-H center dot center dot center dot F, and the layers are further connected by Na+ forming a three-dimensional framework. A transparent crystal with a size up to 5.0 x 2.5 x 1.0 mm(3) has been grown just by controlling the hydrothermal conditions. The crystal morphology, electronic structure, and optical and thermal properties of NTS were analyzed. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000382820000023 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/4858]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | 1.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, DD ,Zhang, FF ,Sun, YZ ,et al. Hydrogen bond-assisted crystallization: structure, growth and characterization of a new mixed-anion transition metal fluoride Na3NH4(TiF6)(SO4)center dot H2O[J]. NEW JOURNAL OF CHEMISTRY,2016,40(9):7407-7413. |
| APA | Xu, DD ,Zhang, FF ,Sun, YZ ,Yang, ZH ,Dong, XY ,&Pan, SL .(2016).Hydrogen bond-assisted crystallization: structure, growth and characterization of a new mixed-anion transition metal fluoride Na3NH4(TiF6)(SO4)center dot H2O.NEW JOURNAL OF CHEMISTRY,40(9),7407-7413. |
| MLA | Xu, DD ,et al."Hydrogen bond-assisted crystallization: structure, growth and characterization of a new mixed-anion transition metal fluoride Na3NH4(TiF6)(SO4)center dot H2O".NEW JOURNAL OF CHEMISTRY 40.9(2016):7407-7413. |
入库方式： OAI收割
来源：新疆理化技术研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。