Three Alkali Metal Lead Orthophosphates - Syntheses, Crystal Structures and Properties of APbPO(4) (A = K, Rb, Cs)
文献类型：期刊论文
| 作者 | Huang, SS (Huang, Shengshi)1; Jing, Q (Jing, Qun)1; Han, J (Han, Jian)1; Pan, SL (Pan, Shilie)1 ; Wu, HP (Wu, Hongping)1; Yang, ZH (Yang, Zhihua)1
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| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
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| 出版日期 | 2015 |
| 期号 | 9页码:1490-1495 |
| 关键词 | Orthophosphates Structure elucidation Alkali metals Lead Density functional calculations |
| 通讯作者 | Han, J |
| 英文摘要 | Three alkali metal lead orthophosphates, APbPO(4) (A = K, Rb, Cs), have been synthesized by conventional solid-state reaction. The single-crystal X-ray structural analyses revealed that they crystallize in the same space group, Pnma (No. 62), but they are not all isostructural. APbPO(4) (A = K, Rb) are isostructural, and the three-dimensional (3D) structure of RbPbPO4 (representative) consists of [Pb1|Rb1O(4)](infinity) chains connected with isolated PO4 tetrahedra, the Pb2|Rb2 atoms filling the pore space. The 3D structure of CsPbPO4 consists of another kind of chains, [PbO4](infinity), connected with isolated PO4 tetrahedra, and the Cs atoms reside in the channel. Thermal, IR spectroscopy, and UV/Vis/NIR diffuse reflectance spectroscopy analyses have also been performed. In addition, first-principle theoretical studies were carried out to aid in the understanding of the electronic structures and the projected density of states of CsPbPO4. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000351435100002 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/4887]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | 1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, SS ,Jing, Q ,Han, J ,et al. Three Alkali Metal Lead Orthophosphates - Syntheses, Crystal Structures and Properties of APbPO(4) (A = K, Rb, Cs)[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2015(9):1490-1495. |
| APA | Huang, SS ,Jing, Q ,Han, J ,Pan, SL ,Wu, HP ,&Yang, ZH .(2015).Three Alkali Metal Lead Orthophosphates - Syntheses, Crystal Structures and Properties of APbPO(4) (A = K, Rb, Cs).EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(9),1490-1495. |
| MLA | Huang, SS ,et al."Three Alkali Metal Lead Orthophosphates - Syntheses, Crystal Structures and Properties of APbPO(4) (A = K, Rb, Cs)".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .9(2015):1490-1495. |
入库方式： OAI收割
来源：新疆理化技术研究所
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