Bronsted acidic ionic liquid-catalyzed dehydrative formation of isosorbide from sorbitol: introduction of a continuous process
文献类型：期刊论文
| 作者 | Deng, Jie1; Xu, Bao-Hua2; Wang, Yao-Feng2; Mo, Xian-En2; Zhang, Rui1; Li, You2; Zhang, Suo-Jiang2 |
| 刊名 | CATALYSIS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2017-05-21 |
| 卷号 | 7期号:10页码:2065-2073 |
| ISSN号 | 2044-4753 |
| DOI | 10.1039/c7cy00512a |
| 文献子类 | Article |
| 英文摘要 | A highly efficient synthesis of isosorbide from sorbitol was developed using Bronsted acidic ionic liquids (BILs) as the catalyst for the first time. The structure-performance relationship was discussed extensively and a proper value of the Gutmann acceptor number (AN) rather than the inherent of acidity was found to be essential for an optimized yield of isosorbide. In addition, the excellent behavior of preferred BIL-4 in the consecutive recycling tests renders the construction of a continuous process probable. Systematic optimization demonstrated that a yield of 82% of isosorbide with a purity of 99.3% could be reached at balance. |
| WOS关键词 | 1-butyl-3-methylimidazolium Hydrogen Sulfate ; Conversion ; Efficient ; Cellulose ; Hexitols ; Fructose ; Isomerization ; Chemistry ; Mechanism ; Cations |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000401907700012 |
| 资助机构 | National Basic Research Program of China (973 Program)(2015CB251401) ; National Natural Science Foundation of China(21476240 ; Instrument Developing Project of the Chinese Academy of Sciences(YZ201521) ; Shanghai education commission key projects of scientific research and innovation(14ZZ061) ; CAS (Chinese Academy of Sciences) 100-Talent Program ; Key Research Program of Frontier Sciences, CAS(QYZDY-SSW-JSCo11 ; 21606238 ; QYZDY-SSW-JSC011) ; 21374029) |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/22528]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,Key Lab Gr, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Deng, Jie,Xu, Bao-Hua,Wang, Yao-Feng,et al. Bronsted acidic ionic liquid-catalyzed dehydrative formation of isosorbide from sorbitol: introduction of a continuous process[J]. CATALYSIS SCIENCE & TECHNOLOGY,2017,7(10):2065-2073. |
| APA | Deng, Jie.,Xu, Bao-Hua.,Wang, Yao-Feng.,Mo, Xian-En.,Zhang, Rui.,...&Zhang, Suo-Jiang.(2017).Bronsted acidic ionic liquid-catalyzed dehydrative formation of isosorbide from sorbitol: introduction of a continuous process.CATALYSIS SCIENCE & TECHNOLOGY,7(10),2065-2073. |
| MLA | Deng, Jie,et al."Bronsted acidic ionic liquid-catalyzed dehydrative formation of isosorbide from sorbitol: introduction of a continuous process".CATALYSIS SCIENCE & TECHNOLOGY 7.10(2017):2065-2073. |
入库方式： OAI收割
来源：过程工程研究所
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