Synthesis, Crystal Structure, and Properties of Energetic Copper(II) Complex based on 3,5-Dinitrobenzoic Acid and 1,5-Diaminotetrazole
文献类型：期刊论文
| 作者 | Li, Zhimin1; Yuan, Yutao1,2; Zhang, Yanqiang1; Liu, Long1,3; Zhang, Suojiang1 |
| 刊名 | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
 |
| 出版日期 | 2017-05-18 |
| 卷号 | 643期号:10页码:647-652 |
| 关键词 | 1,5-Diaminotetrazole 3,5-Dinitrobenzoic acid Copper Energetic complexes Additives |
| ISSN号 | 0044-2313 |
| 英文摘要 | Energetic copper(II) complexes based on 3,5-dinitrobenzoic acid (HDNBA) and 1,5-diaminotetrazole (DAT), Cu(DNBA)(2)(H2O)(2) (1) and Cu(DAT)(2)(DNBA)(2) (2) were synthesized and characterized by elemental analysis, IR spectroscopy, single-crystal and powder X-ray diffraction. In both complexes, Cu-II was coordinated to a plane tetragon, by four oxygen atoms from two DNBA(-) ions and two coordinated H2O molecules for 1, and by two oxygen atoms and two nitrogen atoms from different DNBA(-) ions and DAT ligands for 2. Differential scanning calorimetry (DSC) and thermogravimetry (TG) analyses were employed to measure the thermal decomposition processes and non-isothermal kinetics parameters of the complexes. The thermal decomposition onset temperatures of 1 and 2 are 321 and 177 degrees C. The apparent activation energies of the first exothermic decomposition peaks of 1 and 2 are 247.2 and 185.2 kJmol(-1). Both 1 (35 J, > 360 N) and 2 (12.5 J, > 360 N) are less sensitive than RDX. The catalytic effects on the decomposition of ammonium perchlorate (AP) of 1 and 2 were studied by DSC. All results supported the potential applications of the energetic complexes as additives of solid rocket propellants. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | NITROGEN-RICH ; PHYSICOCHEMICAL PROPERTIES ; SENSITIVITY ; SALTS ; DENSITY |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000402418600005 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/22653]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China 3.Inst Proc Engn, Lab Particle Sci & Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Zhimin,Yuan, Yutao,Zhang, Yanqiang,et al. Synthesis, Crystal Structure, and Properties of Energetic Copper(II) Complex based on 3,5-Dinitrobenzoic Acid and 1,5-Diaminotetrazole[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2017,643(10):647-652. |
| APA | Li, Zhimin,Yuan, Yutao,Zhang, Yanqiang,Liu, Long,&Zhang, Suojiang.(2017).Synthesis, Crystal Structure, and Properties of Energetic Copper(II) Complex based on 3,5-Dinitrobenzoic Acid and 1,5-Diaminotetrazole.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,643(10),647-652. |
| MLA | Li, Zhimin,et al."Synthesis, Crystal Structure, and Properties of Energetic Copper(II) Complex based on 3,5-Dinitrobenzoic Acid and 1,5-Diaminotetrazole".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 643.10(2017):647-652. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。