Production of Bio-Based Gasoline by Noble-Metal-Catalyzed Hydrodeoxygenation of alpha-Angelica Lactone Derived Di/Trimers
文献类型：期刊论文
| 作者 | Ayodele, Olubunmi O.1,2,3; Dawodu, Folasegun A.2; Yan, Dongxia1; Dong, Huixian1; Xin, Jiayu1; Zhang, Suojiang1 |
| 刊名 | CHEMISTRYSELECT
 |
| 出版日期 | 2017-05-23 |
| 卷号 | 2期号:15页码:4219-4225 |
| 关键词 | Angelica lactone biomass C-C coupling catalysts hydrodeoxygenation |
| ISSN号 | 2365-6549 |
| 英文摘要 | Conversion of biomass into a suitable fuel involves series of chemical transformation including C-C coupling and hydrodeoxygenation reactions. Here, we have employed coupling reaction to a biomass-derived angelica lactone in the presence of mild alkaline catalysts, K2CO3 to obtain dimers and trimers in appropriate quantities. Hydrodeoxygenation of these molecules over carbon-supported noble metal catalysts was performed. Subsequently, the effect of operating parameters such as hydrogen pressure, temperature and reaction time on the hydrodeoxygenation of di/trimers were fully optimized and liquids suitable for gasoline application were obtained. This process has the potential of scale-up since the raw materials can easily be obtained from freely available biomass and the technology involved in carbon-carbon coupling and hydrodeoxygenation is well known. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | HIGH-QUALITY DIESEL ; TRANSPORTATION FUELS ; GAMMA-VALEROLACTONE ; CARBON-DIOXIDE ; BIOMASS ; LIQUID ; HYDROCARBONS ; CONVERSION ; HYDROGEN ; ALKANES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000402286000008 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/22658]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Univ Ibadan, Dept Ind Chem, Ibadan, Oyo State, Nigeria 3.Forestry Res Inst Nigeria, Dept Forest Prod Dev & Utilizat, Ibadan, Oyo State, Nigeria |
| 推荐引用方式 GB/T 7714 | Ayodele, Olubunmi O.,Dawodu, Folasegun A.,Yan, Dongxia,et al. Production of Bio-Based Gasoline by Noble-Metal-Catalyzed Hydrodeoxygenation of alpha-Angelica Lactone Derived Di/Trimers[J]. CHEMISTRYSELECT,2017,2(15):4219-4225. |
| APA | Ayodele, Olubunmi O.,Dawodu, Folasegun A.,Yan, Dongxia,Dong, Huixian,Xin, Jiayu,&Zhang, Suojiang.(2017).Production of Bio-Based Gasoline by Noble-Metal-Catalyzed Hydrodeoxygenation of alpha-Angelica Lactone Derived Di/Trimers.CHEMISTRYSELECT,2(15),4219-4225. |
| MLA | Ayodele, Olubunmi O.,et al."Production of Bio-Based Gasoline by Noble-Metal-Catalyzed Hydrodeoxygenation of alpha-Angelica Lactone Derived Di/Trimers".CHEMISTRYSELECT 2.15(2017):4219-4225. |
入库方式： OAI收割
来源：过程工程研究所
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