Synthesis of a (sic)-shaped amphiphilic block copolymer by the combination of atom transfer radical polymerization and living anionic polymerization
文献类型：期刊论文
| 作者 | Yu XF ; Shi TF ; An LJ ; Zhang G ; Dutta PK |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 45期号:1页码:147-156 |
| 关键词 | RING-OPENING POLYMERIZATION EXHIBITING SLOW EQUILIBRIA GRAFT-COPOLYMERS BRANCH-POINTS MIKTOARM STAR CATIONIC-POLYMERIZATION MULTIGRAFT COPOLYMERS DIBLOCK COPOLYMERS SHAPED COPOLYMERS FACILE SYNTHESIS |
| ISSN号 | 0887-624x |
| 通讯作者 | an lj |
| 中文摘要 | the functionalization of monomer units in the form of macroinitiators in an orthogonal fashion yields more predictable macromolecular architectures and complex polymers. therefore, a new there exists e-shaped amphiphilic block copolymer, (pmma)(2)-peo-(ps)(2)-peo-(pmma)(2) [where pmma is poly(methyl methacrylate), peo is poly (ethylene oxide), and ps is polystyrene], has been designed and successfully synthesized by the combination of atom transfer radical polymerization (atrp) and living anionic polymerization. the synthesis of meso-2,3-dibromosuccinic acid acetate/diethylene glycol was used to initiate the polymerization of styrene via atrp to yield linear (ho)(2)-ps2 with two active hydroxyl groups by living anionic polymerization via diphenylmethylpotassium to initiate the polymerization of ethylene oxide. afterwards, the synthesized miktoarm-4 amphiphilic block copolymer, (ho-peo)(2)-ps2, was esterified with 2,2-dichloroacetyl chloride to form a macroinitiator that initiated the polymerization of methyl methacrylate via atrp to prepare the there exists e-shaped amphiphilic block copolymer. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000242873000014 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/13427]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yu XF,Shi TF,An LJ,et al. Synthesis of a (sic)-shaped amphiphilic block copolymer by the combination of atom transfer radical polymerization and living anionic polymerization[J]. journal of polymer science part a-polymer chemistry,2007,45(1):147-156. |
| APA | Yu XF,Shi TF,An LJ,Zhang G,&Dutta PK.(2007).Synthesis of a (sic)-shaped amphiphilic block copolymer by the combination of atom transfer radical polymerization and living anionic polymerization.journal of polymer science part a-polymer chemistry,45(1),147-156. |
| MLA | Yu XF,et al."Synthesis of a (sic)-shaped amphiphilic block copolymer by the combination of atom transfer radical polymerization and living anionic polymerization".journal of polymer science part a-polymer chemistry 45.1(2007):147-156. |
入库方式： OAI收割
来源：长春应用化学研究所
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