中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A simple route to incorporate redox mediator into carbon nanotubes/Nafion composite film and its application to determine NADH at low potential

文献类型:期刊论文

作者Huang MH ; Jiang HQ ; Zhai JF ; Liu BF ; Dong SJ
刊名talanta
出版日期2007
卷号74期号:1页码:132-139
关键词NICOTINAMIDE ADENINE-DINUCLEOTIDE ELECTROCATALYTIC OXIDATION ELECTROCHEMICAL OXIDATION AMPEROMETRIC BIOSENSORS MODIFIED ELECTRODES GRAPHITE ELECTRODE SYSTEM BLUE DYES DEHYDROGENASE
ISSN号0039-9140
通讯作者dong sj
中文摘要through a new and simple ion-exchange route, two-electron redox mediator thionine has been deliberately incorporated into the carbon nanotubes (cnts)/nafion composite film due to the fact that there is strong interaction between any of two among the three materials (ion-exchange process between thionine and nafion, strong adsorption of thionine by cnts, and wrapping and solubilizing of cnts with nation). the good homogenization of electron conductor cnts in the integrated films provides the possibility of three-dimensional electron conductive network. the resulting integrated films exhibited high and stable electrocatalytic activity toward nadh oxidation with the significant decrease of high overpotential, which responds more sensitively more than those modified by thioine or cnts alone. such high electrocatalytic activity facilitated the low potential determination of nadh (as low as -0.1 v), which eliminated the interferences from other easily oxidizable species. in a word, the immobilization approach is very simple, timesaving and effective, which could be extended to the immobilization of other cationic redox mediators into the cnts/nafion composite film. and these features may offer potential promise for the design of amperometric biosensors.
收录类别SCI
语种英语
WOS记录号WOS:000251333700018
公开日期2010-07-13
源URL[http://ir.ciac.jl.cn/handle/322003/13487]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Huang MH,Jiang HQ,Zhai JF,et al. A simple route to incorporate redox mediator into carbon nanotubes/Nafion composite film and its application to determine NADH at low potential[J]. talanta,2007,74(1):132-139.
APA Huang MH,Jiang HQ,Zhai JF,Liu BF,&Dong SJ.(2007).A simple route to incorporate redox mediator into carbon nanotubes/Nafion composite film and its application to determine NADH at low potential.talanta,74(1),132-139.
MLA Huang MH,et al."A simple route to incorporate redox mediator into carbon nanotubes/Nafion composite film and its application to determine NADH at low potential".talanta 74.1(2007):132-139.

入库方式: OAI收割

来源:长春应用化学研究所

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