A simple route to incorporate redox mediator into carbon nanotubes/Nafion composite film and its application to determine NADH at low potential
文献类型:期刊论文
作者 | Huang MH ; Jiang HQ ; Zhai JF ; Liu BF ; Dong SJ |
刊名 | talanta
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出版日期 | 2007 |
卷号 | 74期号:1页码:132-139 |
关键词 | NICOTINAMIDE ADENINE-DINUCLEOTIDE ELECTROCATALYTIC OXIDATION ELECTROCHEMICAL OXIDATION AMPEROMETRIC BIOSENSORS MODIFIED ELECTRODES GRAPHITE ELECTRODE SYSTEM BLUE DYES DEHYDROGENASE |
ISSN号 | 0039-9140 |
通讯作者 | dong sj |
中文摘要 | through a new and simple ion-exchange route, two-electron redox mediator thionine has been deliberately incorporated into the carbon nanotubes (cnts)/nafion composite film due to the fact that there is strong interaction between any of two among the three materials (ion-exchange process between thionine and nafion, strong adsorption of thionine by cnts, and wrapping and solubilizing of cnts with nation). the good homogenization of electron conductor cnts in the integrated films provides the possibility of three-dimensional electron conductive network. the resulting integrated films exhibited high and stable electrocatalytic activity toward nadh oxidation with the significant decrease of high overpotential, which responds more sensitively more than those modified by thioine or cnts alone. such high electrocatalytic activity facilitated the low potential determination of nadh (as low as -0.1 v), which eliminated the interferences from other easily oxidizable species. in a word, the immobilization approach is very simple, timesaving and effective, which could be extended to the immobilization of other cationic redox mediators into the cnts/nafion composite film. and these features may offer potential promise for the design of amperometric biosensors. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000251333700018 |
公开日期 | 2010-07-13 |
源URL | [http://ir.ciac.jl.cn/handle/322003/13487] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Huang MH,Jiang HQ,Zhai JF,et al. A simple route to incorporate redox mediator into carbon nanotubes/Nafion composite film and its application to determine NADH at low potential[J]. talanta,2007,74(1):132-139. |
APA | Huang MH,Jiang HQ,Zhai JF,Liu BF,&Dong SJ.(2007).A simple route to incorporate redox mediator into carbon nanotubes/Nafion composite film and its application to determine NADH at low potential.talanta,74(1),132-139. |
MLA | Huang MH,et al."A simple route to incorporate redox mediator into carbon nanotubes/Nafion composite film and its application to determine NADH at low potential".talanta 74.1(2007):132-139. |
入库方式: OAI收割
来源:长春应用化学研究所
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