中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Electrochemical characteristics of glucose oxidase adsorbed at carbon nanotubes modified electrode with ionic liquid as binder

文献类型:期刊论文

作者Liu Y ; Liu L ; Dong SJ
刊名electroanalysis
出版日期2007
卷号19期号:1页码:55-59
关键词AMPEROMETRIC BIOSENSORS BIOELECTROCHEMISTRY FABRICATION CHITOSAN SYSTEMS MATRIX NAFION FILMS
ISSN号1040-0397
通讯作者dong sj
中文摘要multiwall carbon nanotubes (cnts)-modified electrode has been prepared by using ionic liquid (il) as the binder. the as-prepared cnts-il composite modified electrode has good biocompatibility and is a suitable matrix to immobilize biomolecules. glucose oxidase (gox), containing flavin adenine dinucleotide as active site, stably adsorbed on modified electrode surface has resulted in the direct electron transfer. the electron transfer rate of 9.08 s(-1) obtained is much higher than that of gox adsorbed on the cnts papers (1.7 s(-1)), and the process is more reversible with small redox peak separation of 23 mv this may be due to the synergetic promotion of cnts and il to electron transfer of the protein, especially the il as the binder, showing better electrochemical properties than that of chitosan and nafion. furthermore, gox adsorbed at the modified electrode exhibits good stability and keeps good electrocatalytic activity to glucose with broad linear range up to 20 mm. besides, the simple preparation procedure and easy renewability make the system a basis to investigate the electron transfer kinetics and biocatalytic performance of gox and provide a promising platform for the development of biosensors.
收录类别SCI
语种英语
WOS记录号WOS:000243443000007
公开日期2010-07-13
源URL[http://ir.ciac.jl.cn/handle/322003/13493]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Liu Y,Liu L,Dong SJ. Electrochemical characteristics of glucose oxidase adsorbed at carbon nanotubes modified electrode with ionic liquid as binder[J]. electroanalysis,2007,19(1):55-59.
APA Liu Y,Liu L,&Dong SJ.(2007).Electrochemical characteristics of glucose oxidase adsorbed at carbon nanotubes modified electrode with ionic liquid as binder.electroanalysis,19(1),55-59.
MLA Liu Y,et al."Electrochemical characteristics of glucose oxidase adsorbed at carbon nanotubes modified electrode with ionic liquid as binder".electroanalysis 19.1(2007):55-59.

入库方式: OAI收割

来源:长春应用化学研究所

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