Sensitive biomimetic sensor based on molecular imprinting at functionalized indium tin oxide electrodes
文献类型:期刊论文
作者 | Gao N ; Xu Z ; Wang F ; Dong SJ |
刊名 | electroanalysis
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出版日期 | 2007 |
卷号 | 19期号:16页码:1655-1660 |
关键词 | ACOUSTIC-WAVE SENSOR SOL-GEL SELECTIVE RECOGNITION POLYMER MEMBRANES BIOSENSOR TEMPLATE FILMS EXTRACTION STRATEGIES ELEMENTS |
ISSN号 | 1040-0397 |
通讯作者 | dong sj |
中文摘要 | we initially report an electrochemical sensing platform based on molecularly imprinted polymers (mips) at functionalized indium tin oxide electrodes (ito). in this research, aminopropyl-derivatized organosilane aminopropyltriethoxysilane (aptes), which plays the role of functional monomers for template recognition, was firstly self-assembled on an ito electrode and then dopamine-imprinted sol was spin-coated on the modified surface. aptes which can interact with template dopamine (da) through hydrogen bonds brought more binding sites located closely to the surface of the ito electrode, thus made the prepared sensor more sensitive for da detection. potential scanning is presented to extract da from the modified film, thus da can rapidly and completely leach out. the affinity and selectivity of the resulting biomimetic sensor were characterized using cyclic voltammetry (cv). it exhibited an increased affinity for da over that of structurally related molecules, the anodic current for da oxidation depended on the concentration of da in the linear range from 2 x 10(-6) m to 0.8 x 10(-3) m with a correlation coefficient of 0.9927.in contrast, da-templated film prepared under identical conditions on a bare ito showed obviously lower response toward dopamine in solution. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000249057800001 |
公开日期 | 2010-07-13 |
源URL | [http://ir.ciac.jl.cn/handle/322003/13495] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Gao N,Xu Z,Wang F,et al. Sensitive biomimetic sensor based on molecular imprinting at functionalized indium tin oxide electrodes[J]. electroanalysis,2007,19(16):1655-1660. |
APA | Gao N,Xu Z,Wang F,&Dong SJ.(2007).Sensitive biomimetic sensor based on molecular imprinting at functionalized indium tin oxide electrodes.electroanalysis,19(16),1655-1660. |
MLA | Gao N,et al."Sensitive biomimetic sensor based on molecular imprinting at functionalized indium tin oxide electrodes".electroanalysis 19.16(2007):1655-1660. |
入库方式: OAI收割
来源:长春应用化学研究所
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