Guanidine/Pd(OAc)(2)-catalyzed room temperature Suzuki cross-coupling reaction in aqueous media under aerobic conditions
文献类型：期刊论文
| 作者 | Li SH ; Lin YJ ; Cao JG ; Zhang SB |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 72期号:11页码:4067-4072 |
| 关键词 | HETEROCYCLIC CARBENE LIGANDS HINDERED ARYL CHLORIDES CATALYZED HECK REACTION HIGHLY EFFICIENT PALLADIUM NANOPARTICLES ARYLBORONIC ACIDS PHOSPHINE-LIGANDS MILD CONDITIONS IONIC LIQUIDS MIYAURA REACTIONS |
| ISSN号 | 0022-3263 |
| 通讯作者 | zhang sb |
| 中文摘要 | a highly efficient pd(oac)(2)/guanidine aqueous system for the room temperature suzuki cross-coupling reaction has been developed. the new water-soluble and air-stable catalyst pd(oac)(2)(.)(1f)(2) from pd(oac)(2) and 1,1,3,3-tetramethyl-2-n-butylguanidine (1f) was synthesized and characterized by x-ray crystallography. in the presence of pd(oac)(2)(.)(1f)(2), coupling of arylboronic acids with a wide range of aryl halides, including aryl iodides, aryl bromides, even activated aryl chlorides, was carried out smoothly in aqueous solvent to afford the cross-coupling products in good to excellent yields and high turnover numbers (tons) (tons up to 850 000 for the reaction of 1-iodo-4-nitrobenzene and phenylboronic acid). furthermore, this mild protocol could tolerate a broad range of functional groups. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000246570200010 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/13759]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li SH,Lin YJ,Cao JG,et al. Guanidine/Pd(OAc)(2)-catalyzed room temperature Suzuki cross-coupling reaction in aqueous media under aerobic conditions[J]. journal of organic chemistry,2007,72(11):4067-4072. |
| APA | Li SH,Lin YJ,Cao JG,&Zhang SB.(2007).Guanidine/Pd(OAc)(2)-catalyzed room temperature Suzuki cross-coupling reaction in aqueous media under aerobic conditions.journal of organic chemistry,72(11),4067-4072. |
| MLA | Li SH,et al."Guanidine/Pd(OAc)(2)-catalyzed room temperature Suzuki cross-coupling reaction in aqueous media under aerobic conditions".journal of organic chemistry 72.11(2007):4067-4072. |
入库方式： OAI收割
来源：长春应用化学研究所
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