Synthesis, structure and photochromic properties of a novel 1,6-hexanediamine trimolybdate supramolecular compound
文献类型：期刊论文
| 作者 | Sun DH ; Zhang HJ ; Zhang JL ; Zheng GL ; Yu JB ; Gao SY |
| 刊名 | journal of solid state chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 180期号:1页码:393-399 |
| 关键词 | CRYSTAL-STRUCTURE HYDROTHERMAL SYNTHESIS POLYOXOMETALATE CLUSTER SPECTROSCOPY COMPLEX DAWSON FILMS |
| ISSN号 | 0022-4596 |
| 通讯作者 | zhang hj |
| 中文摘要 | a novel supramolecular compound 1,6-hexanediamine trimolybdate ((c6h18n2[mo3o10], denoted as hdamo) has been synthesized by a hydrothermal method and its structure has been characterized by elemental analyses, fourier transform infrared (ft-ir) spectra, single-crystal x-ray diffraction (xrd) technique. this single crystal compound consists of protonated 1,6-hexanediamine (hda) cations and polyoxometalate [mo3o10](2-) anions. its crystal structure belongs to monoclinic system (space group p2(1)/n) with a = 7.7508(14), b = 11.467(2), c = 16.167(3) angstrom, beta = 92.689(3)degrees, v = 143 5.3(5) angstrom(3), z = 4 and d-ealc = 2.619 g cm(-3). the final statistics based on f-2 are gof = 0.980, r-1 = 0.0261 and wr(2) = 0.0506 for i > 2 sigma(i). xrd analysis revealed that in the crystal structure of hdamo, novel infinite [mo3o10](2-) chains parallel to a axis are made up of distorted moo6 octahedra connected by corners and edges. the protonated hda cations occupy channels formed by [mo(3)o3(10)](2-) chains and exhibit strong hydrogen bond interactions to terminal and bridging oxo groups of the chains. the [mo3o10](2-) chains linked through protonated had cations formed a one-dimensional network. the hdamo compound shows novel photochromic properties, i.e., its color changes from white to reddish brown gradually under uv irradiation. xrd, ft-ir, esr spectra and xps are used to investigate the photochromic behavior of the compound. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000243951900053 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/13809]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Sun DH,Zhang HJ,Zhang JL,et al. Synthesis, structure and photochromic properties of a novel 1,6-hexanediamine trimolybdate supramolecular compound[J]. journal of solid state chemistry,2007,180(1):393-399. |
| APA | Sun DH,Zhang HJ,Zhang JL,Zheng GL,Yu JB,&Gao SY.(2007).Synthesis, structure and photochromic properties of a novel 1,6-hexanediamine trimolybdate supramolecular compound.journal of solid state chemistry,180(1),393-399. |
| MLA | Sun DH,et al."Synthesis, structure and photochromic properties of a novel 1,6-hexanediamine trimolybdate supramolecular compound".journal of solid state chemistry 180.1(2007):393-399. |
入库方式： OAI收割
来源：长春应用化学研究所
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