Supramolecular architectures, photophysics, and electroluminescence of 1,3,4-oxadiazole-based iridium(III) complexes: From mu-dichloro bridged dimer to mononuclear complexes
文献类型：期刊论文
| 作者 | Chen LQ ; Yang CL ; Li M ; Qin JG ; Gao J ; You H ; Ma DG |
| 刊名 | crystal growth & design
 |
| 出版日期 | 2007 |
| 卷号 | 7期号:1页码:39-46 |
| 关键词 | LIGHT-EMITTING-DIODES EXCITED-STATE PROPERTIES CONJUGATED POLYMERS EFFICIENT DEVICES LIGANDS ELECTROCHEMISTRY IR(III) OLEDS |
| ISSN号 | 1528-7483 |
| 通讯作者 | yang cl |
| 中文摘要 | one mu-dichloro bridged diiridium complex and three mononuclear iridium(iii) complexes based on the 1,3,4-oxadiazole derivatives as cyclometalated ligands and acetylacetonate (acac) or dithiolates o,o'-diethyldithiophosphate (et(2)dtp) or n,n'-diethyldithiocarbamate (et(2)dtc) as ancillary ligands have been synthesized and systematically studied by x-ray diffraction analysis. the results reveal that three mononuclear complexes all adopt distorted octahedral coordination geometry around the iridium center by two chelating ligands with cis-c-c and trans-n-n dispositions, which have the same coordination mode as the diiridium dimer. the dinuclear complex crystallizes in the monoclinic system and space group c2/c, whereas three mononuclear iridium complexes are all triclinic system and space group p(1) over bar. in the stacking structure of the dimer, one-dimensional tape-like chains along the b-axis are formed by hydrogen bondings, which are strengthened by pi stacking interactions between phenyl rings of 1,3,4-oxadiazole ligands. then these chains assemble a three-dimensional alternating peak and valley fused wave-shape structure. in each stacking structure of three mononuclear complexes, two molecules form a dimer by the c-h center dot center dot center dot o hydrogen bondings, and these dimers are connected by pi stacking interactions along the b-axis, constructing a zigzag chain. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000243195200009 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/13961]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Chen LQ,Yang CL,Li M,et al. Supramolecular architectures, photophysics, and electroluminescence of 1,3,4-oxadiazole-based iridium(III) complexes: From mu-dichloro bridged dimer to mononuclear complexes[J]. crystal growth & design,2007,7(1):39-46. |
| APA | Chen LQ.,Yang CL.,Li M.,Qin JG.,Gao J.,...&Ma DG.(2007).Supramolecular architectures, photophysics, and electroluminescence of 1,3,4-oxadiazole-based iridium(III) complexes: From mu-dichloro bridged dimer to mononuclear complexes.crystal growth & design,7(1),39-46. |
| MLA | Chen LQ,et al."Supramolecular architectures, photophysics, and electroluminescence of 1,3,4-oxadiazole-based iridium(III) complexes: From mu-dichloro bridged dimer to mononuclear complexes".crystal growth & design 7.1(2007):39-46. |
入库方式： OAI收割
来源：长春应用化学研究所
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