Selective hydrogenation of citral with transition metal complexes in supercritical carbon dioxide
文献类型：期刊论文
| 作者 | Liu RX ; Zhao FY ; Fujita S ; Arai M |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2007 |
| 卷号 | 316期号:2页码:127-133 |
| 关键词 | LIQUID-PHASE HYDROGENATION ALPHA RUTHENIUM CATALYSTS CO2 MEDIUM CINNAMALDEHYDE CROTONALDEHYDE PRESSURE ACROLEIN SOLVENTS SUPPORT BETA-UNSATURATED ALDEHYDES |
| ISSN号 | 0926-860x |
| 通讯作者 | zhao fy |
| 中文摘要 | the activity and selectivity of the transition metal complexes formed from ru, rh, pd and ni with triphenylphosphine (tpp) have been investigated for hydrogenation of citral in supercritical carbon dioxide (scco(2)). high activities are obtained with ru/tpp and pd/tpp catalysts, and the overall activity is in the order of pd approximate to ru > rh > ni. the ru/tpp complex is highly selective to the formation of unsaturated alcohols of geraniol and nerol. in contrast, the pd/tpp catalyst is more selective to partially saturated aldehydes of citronellal. furthermore, the influence of several parameters such as co2 and h-2 pressures, n-2 pressure and reaction time has been discussed. co2 pressure has a significant impact on the product distribution, and the selectivity for geraniol and nerol can be enhanced from 27% to 75% with increasing co2 pressure from 6 to 16 mpa, while the selectivity for citronellol decreases from 70% to 20%. striking changes in the conversion and product distribution in scco(2) could be interpreted with variations in the phase behavior and the molecular interaction between co2 and the substrate in the gas phase and in the liquid phase. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000243664900001 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/14087]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu RX,Zhao FY,Fujita S,et al. Selective hydrogenation of citral with transition metal complexes in supercritical carbon dioxide[J]. applied catalysis a-general,2007,316(2):127-133. |
| APA | Liu RX,Zhao FY,Fujita S,&Arai M.(2007).Selective hydrogenation of citral with transition metal complexes in supercritical carbon dioxide.applied catalysis a-general,316(2),127-133. |
| MLA | Liu RX,et al."Selective hydrogenation of citral with transition metal complexes in supercritical carbon dioxide".applied catalysis a-general 316.2(2007):127-133. |
入库方式： OAI收割
来源：长春应用化学研究所
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