Water-resistant conducting hybrids from electrostatic interactions
文献类型:期刊论文
作者 | Luo J ; Wang QG ; Wang XH ; Li J ; Zhao XJ ; Wang FS |
刊名 | journal of polymer science part a-polymer chemistry
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出版日期 | 2007 |
卷号 | 45期号:8页码:1424-1431 |
关键词 | INORGANIC COMPOSITE-MATERIALS SOL-GEL PROCESS POLYMER BLENDS POLYANILINE ACID PERCOLATION TRANSPORT CORROSION NETWORKS FILMS |
ISSN号 | 0887-624x |
通讯作者 | wang xh |
中文摘要 | conductive hybrids were prepared in a water/ethanol solution via the solgel process from an inorganic sol containing carboxyl groups and water-borne conductive polyaniline (cpani). the inorganic sol was prepared by the hydrolysis and condensation of methyltriethoxysilane with the condensed product of maleic anhydride and aminopropyltriethoxysilane as a catalyst, for which the carboxyl counterion along the cpani backbone acted as an electrostatic-interaction moiety. the existence of this electrostatic interaction could improve the compatibility of the two components and contribute to the homogeneous dispersion of cpani in the silica phase. the electrostaticinteraction hybrids displayed a conductivity percolation threshold as low as 1.1 wt % polyaniline in an emeraldine base, showing 2 orders of magnitude higher electrical conductivity than that without electrostatic interactions. the electrostatic-interaction hybrids also showed good water resistance; the electrical conductivity with a cpani loading of 16 wt % underwent a slight change after 14 days of soaking in water. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000245347100006 |
公开日期 | 2010-07-13 |
源URL | [http://ir.ciac.jl.cn/handle/322003/14135] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Luo J,Wang QG,Wang XH,et al. Water-resistant conducting hybrids from electrostatic interactions[J]. journal of polymer science part a-polymer chemistry,2007,45(8):1424-1431. |
APA | Luo J,Wang QG,Wang XH,Li J,Zhao XJ,&Wang FS.(2007).Water-resistant conducting hybrids from electrostatic interactions.journal of polymer science part a-polymer chemistry,45(8),1424-1431. |
MLA | Luo J,et al."Water-resistant conducting hybrids from electrostatic interactions".journal of polymer science part a-polymer chemistry 45.8(2007):1424-1431. |
入库方式: OAI收割
来源:长春应用化学研究所
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