中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Self-assembly of diblock copolymer mixtures in confined states: A Monte Carlo study

文献类型:期刊论文

作者Zhu YT ; Jiang W
刊名macromolecules
出版日期2007
卷号40期号:8页码:2872-2881
关键词CONSISTENT-FIELD CALCULATIONS THIN-FILMS BLOCK-COPOLYMERS CYLINDRICAL CONFINEMENT SIMULATIONS MORPHOLOGIES SURFACES POLYMERS
ISSN号0024-9297
通讯作者jiang w
中文摘要the self-assembly of diblock copolymer mixtures (a-b-b/a-b-c or a-b-b/b-b-c mixtures) subjected to cylindrical confinement (two-dimensional confinement) was investigated using a monte carlo method. in this study, the boundary surfaces were configured to attract blocks a but repel blocks b and c. relative to the structures of the individual components, the self-assembled structures of mixtures of the diblock copolymers were more complex and interesting. under cylindrical confinement, with varying cylinder diameters and interaction energies between the boundary surfaces and the blocks, we observed a variety of interesting morphologies. upon decreasing the cylinder's diameter, the self-assembled structures of the a(15)b(15)/a(15)c(15) mixtures changed from double-helix/cylinder structures (blocks b and c formed double helices, whereas blocks a formed the outer barrel and inner core) to stacked disk/cylinder structures (blocks b and c formed the stacked disk core, blocks a formed the outer cylindrical barrel), whereas the self-assembled structures of the a(15)b(7)/b7c15 mixtures changed from concentric cylindrical barrel structures to screw/cylinder structures (blocks c formed an inside core winding with helical stripes, whereas blocks a and b formed the outer cylindrical barrels) and then finally to the stacked disk/cylinder structures.
收录类别SCI
语种英语
WOS记录号WOS:000245549700031
公开日期2010-07-13
源URL[http://ir.ciac.jl.cn/handle/322003/14163]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Zhu YT,Jiang W. Self-assembly of diblock copolymer mixtures in confined states: A Monte Carlo study[J]. macromolecules,2007,40(8):2872-2881.
APA Zhu YT,&Jiang W.(2007).Self-assembly of diblock copolymer mixtures in confined states: A Monte Carlo study.macromolecules,40(8),2872-2881.
MLA Zhu YT,et al."Self-assembly of diblock copolymer mixtures in confined states: A Monte Carlo study".macromolecules 40.8(2007):2872-2881.

入库方式: OAI收割

来源:长春应用化学研究所

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