Evaluation of coverage of self-assembled polyaniline-analogue monolayer by capacitance measurements
文献类型：期刊论文
| 作者 | Niu L ; Kvarnstrom C ; Ivaska A |
| 刊名 | journal of electroanalytical chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 600期号:1页码:95-102 |
| 关键词 | CONDUCTING POLYMER-FILMS COATED GOLD ELECTRODES ELECTROCHEMICAL DEPOSITION MORPHOLOGY CONTROL POLYPYRROLE SURFACES VOLTAMMETRY BARE AREA |
| ISSN号 | 0022-0728 |
| 通讯作者 | ivaska a |
| 中文摘要 | a method is developed to estimate the coverage of an electropolymerizable aniline-analogue monolayer (mixture of 2- and 3-aminophenols, 2/3-atp) by measuring the charge capacitance of the electrode (theta = 81%). the technique of filling the uncovered area (defect sites) of the aniline-analogue monolayer with alkanethiols with long alkane chains (1-decanethiol, 1-dt) has been used to determine the coverage. the dielectric constant (permittivity) of the pani-analogue monolayer was determined to 8.4. adsorption kinetics of 1-dt was also studied, and the value of the rate constant of the secondary adsorption was measured to 0.9 mol(-1) dm(3) s(-1). |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000244013400011 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/14331]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Niu L,Kvarnstrom C,Ivaska A. Evaluation of coverage of self-assembled polyaniline-analogue monolayer by capacitance measurements[J]. journal of electroanalytical chemistry,2007,600(1):95-102. |
| APA | Niu L,Kvarnstrom C,&Ivaska A.(2007).Evaluation of coverage of self-assembled polyaniline-analogue monolayer by capacitance measurements.journal of electroanalytical chemistry,600(1),95-102. |
| MLA | Niu L,et al."Evaluation of coverage of self-assembled polyaniline-analogue monolayer by capacitance measurements".journal of electroanalytical chemistry 600.1(2007):95-102. |
入库方式： OAI收割
来源：长春应用化学研究所
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