Polyelectrolyte complexes of chitosan and phosphotungstic acid as proton-conducting membranes for direct methanol fuel cells
文献类型：期刊论文
| 作者 | Cui ZM ; Liu CP ; Lu TH ; Xing W |
| 刊名 | journal of power sources
 |
| 出版日期 | 2007 |
| 卷号 | 167期号:1页码:94-99 |
| 关键词 | POLYMER ELECTROLYTE MEMBRANES SOL-GEL MEMBRANES COMPOSITE MEMBRANES EXCHANGE MEMBRANES TUNGSTOPHOSPHORIC ACID POLYBENZIMIDAZOLE CROSSOVER TRANSPORT |
| ISSN号 | 0378-7753 |
| 通讯作者 | xing w |
| 中文摘要 | polyelectrolyte complexes (pecs) of chitosan and phosphotungstic acid have been prepared and evaluated as novel proton-conducting membranes for direct methanol fuel cells. phosphotungstic acid can be fixed within pecs membranes through strong electrostatic interactions, which avoids the decrease of conductivity caused by the dissolving of phosphotungstic acid as previously reported. scanning electron microscopy (sem) shows that the pecs membranes are homogeneous and dense. fourier transform infrared spectroscopy (ftir) demonstrates that hydrogen bonding is formed between chitosan and phosphotungstic acid. thermogravimetric analysis (tga) shows that the pecs membranes have good thermal stability up to 210 degrees c. the pecs membranes exhibit good swelling properties and low methanol permeability (p, 3.3 x 10(-7) cm(2) s(-1)). proton conductivity (sigma) of the pecs membranes increases at elevated temperature, reaching the value of 0.024 s cm(-1) at 80 degrees c. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000246256300016 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/14337]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Cui ZM,Liu CP,Lu TH,et al. Polyelectrolyte complexes of chitosan and phosphotungstic acid as proton-conducting membranes for direct methanol fuel cells[J]. journal of power sources,2007,167(1):94-99. |
| APA | Cui ZM,Liu CP,Lu TH,&Xing W.(2007).Polyelectrolyte complexes of chitosan and phosphotungstic acid as proton-conducting membranes for direct methanol fuel cells.journal of power sources,167(1),94-99. |
| MLA | Cui ZM,et al."Polyelectrolyte complexes of chitosan and phosphotungstic acid as proton-conducting membranes for direct methanol fuel cells".journal of power sources 167.1(2007):94-99. |
入库方式： OAI收割
来源：长春应用化学研究所
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