Hydrothermal synthesis, structure characterization of a new mixed Mo/V metal-oxygen cluster compound: [Co(phen)(3)](2)[HPMo4V (Mo4V6IV)-V-VI M2O44]center dot 4H(2)O, (M=0.78Mo(V)+0.22V(IV))
文献类型：期刊论文
| 作者 | Sun YH ; Li XP ; Sun DH ; Niu L ; Xu JQ |
| 刊名 | polish journal of chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 81期号:9页码:1567-1575 |
| 关键词 | CHEMISTRY POLYOXOMETALATE POLYANION |
| ISSN号 | 0137-5083 |
| 通讯作者 | niu l |
| 中文摘要 | a new polyoxometalate [co(phen)(3)](2)[hpmo4v mo-4(vi) v-6(iv) m2o44]center dot 4h(2)o (m = 0.78mo(v)+ 0.22v(iv)) 1 was hydrothermally synthesized and characterized by ir, elemental analyses, x-ray photoelectron spectrum, esr and single crystal x-ray diffraction. the title compound is in the triclinic space group p (1) over bar with a = 12.0953(7) angstrom, b = 14.0182(6) angstrom, c = 14.6468(7) angstrom, v=2402.55(18) angstrom(3), alpha = 105.134(2), beta = 91.841(3), gamma = 91.401(2), z = 1, and r-1 (wr(2)) = 0.0617 (0.1701). the compound was prepared from tetra-capped pseudo-kepin with phosphorus-centered polyoxoanions [pmo8v6m2o44](5-) , [co(phen)(3)](2+) cations and linked through hydrogen bonds and pi-pi stacking interaction into three-dimensional supramolecular framework. astudy of the magnetic properties of 1 demonstrates that it exhibits antiferromagnetic coupling interactions. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000249861700005 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/14483]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Sun YH,Li XP,Sun DH,et al. Hydrothermal synthesis, structure characterization of a new mixed Mo/V metal-oxygen cluster compound: [Co(phen)(3)](2)[HPMo4V (Mo4V6IV)-V-VI M2O44]center dot 4H(2)O, (M=0.78Mo(V)+0.22V(IV))[J]. polish journal of chemistry,2007,81(9):1567-1575. |
| APA | Sun YH,Li XP,Sun DH,Niu L,&Xu JQ.(2007).Hydrothermal synthesis, structure characterization of a new mixed Mo/V metal-oxygen cluster compound: [Co(phen)(3)](2)[HPMo4V (Mo4V6IV)-V-VI M2O44]center dot 4H(2)O, (M=0.78Mo(V)+0.22V(IV)).polish journal of chemistry,81(9),1567-1575. |
| MLA | Sun YH,et al."Hydrothermal synthesis, structure characterization of a new mixed Mo/V metal-oxygen cluster compound: [Co(phen)(3)](2)[HPMo4V (Mo4V6IV)-V-VI M2O44]center dot 4H(2)O, (M=0.78Mo(V)+0.22V(IV))".polish journal of chemistry 81.9(2007):1567-1575. |
入库方式： OAI收割
来源：长春应用化学研究所
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