High-dimensional assembly depending on polyoxoanion templates, metal ion coordination geometries, and a flexible bis(imidazole) ligand
文献类型：期刊论文
| 作者 | Dong BX ; Peng J ; Gomez-Garcia CJ ; Benmansour S ; Jia HQ ; Hu NH |
| 刊名 | inorganic chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 46期号:15页码:5933-5941 |
| ISSN号 | 0020-1669 |
| 关键词 | NUCLEARITY SPIN CLUSTERS HYDROTHERMAL SYNTHESIS 3-DIMENSIONAL FRAMEWORK MAGNETIC-PROPERTIES CRYSTAL-STRUCTURES BUILDING-BLOCKS POLYOXOMETALATE CHEMISTRY PHYSICAL-CHARACTERIZATION ORGANIC FRAMEWORKS COMPLEX FRAGMENTS |
| 通讯作者 | peng j |
| 中文摘要 | by introducing the flexible 1,1'-(1,4-butanediyl)bis(imidazole) (bbi) ligand into the polyoxovanadate system, five novel polyoxoanion-templated architectures based on [as8v14o42](4-) and [v16o38cl](6-) building blocks were obtained: [m(bbi)(2)](2)[as8v14o42(h2o)] [m = co (1), ni (2), and zn (3)], [cu(bbi)](4)[as8v14o42(h2o)] (4), and [cu(bbi)](6)[v16o38cl] (5). compounds 1-3 are isostructural, and they exhibit a binodal (4,6)-connected 2d structure with schlafli symbol (3(4)center dot 4(2))(3(4)center dot 4(4)center dot 5(4)center dot 6(3))(2), in which the polyoxoanion induces a closed four-membered circuit of m-4(bbi)(4). compound 4 exhibits an interesting 3d framework constructed from tetradentate [as8v14o42](4-) cluster anions and cationic ladderlike double chains. there exists a bigger m-8(bbi)(6)o-2 circuit in 4. the 3d extended structure of 5 is composed of heptadentate [v16o38cl](6-) anions and flexural cationic chains; the latter consists of six cu(bbi) segments arranged alternately. it presents the largest 24-membered circuit of m-24(bbi)(24) so far observed made of bbi molecules and transition-metal cations. investigation of their structural relations shows the important template role of the polyoxoanions and the synergetic interactions among the polyoxoanions, transition-metal ions, and flexible ligand in the assembly process. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000248011300021 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/14593]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Dong BX,Peng J,Gomez-Garcia CJ,et al. High-dimensional assembly depending on polyoxoanion templates, metal ion coordination geometries, and a flexible bis(imidazole) ligand[J]. inorganic chemistry,2007,46(15):5933-5941. |
| APA | Dong BX,Peng J,Gomez-Garcia CJ,Benmansour S,Jia HQ,&Hu NH.(2007).High-dimensional assembly depending on polyoxoanion templates, metal ion coordination geometries, and a flexible bis(imidazole) ligand.inorganic chemistry,46(15),5933-5941. |
| MLA | Dong BX,et al."High-dimensional assembly depending on polyoxoanion templates, metal ion coordination geometries, and a flexible bis(imidazole) ligand".inorganic chemistry 46.15(2007):5933-5941. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。