Synthesis and structural characterization of new tungsten(VI) complexes with polycarboxylate ligands
文献类型：期刊论文
| 作者 | Li DM ; Cui LF ; Xing YH ; Xu JQ ; Yu JH ; Wang TG ; Jia HQ ; Hu NH |
| 刊名 | journal of molecular structure
 |
| 出版日期 | 2007 |
| 卷号 | 832期号:1-3页码:138-145 |
| 关键词 | IRON-MOLYBDENUM COFACTOR CRYSTAL-STRUCTURE OXOMOLYBDENUM(VI) COMPLEXES SPECTROSCOPIC PROPERTIES THERMAL-DECOMPOSITION CITRIC-ACID NITROGENASE CITRATE CLUSTERS SINGLE |
| ISSN号 | 0022-2860 |
| 通讯作者 | li dm |
| 中文摘要 | the reactions of (nh4)(2)ws4 and three polycarboxylate ligands {including nitrilotriacetate (nta(3-)), citrate (hcit(3-)) and ethylenediaminetetra acetate (edta(4-))} in h2o/etoh at ambient temperature have resulted in three new trioxotungsten (vi) complexes, k-3[wo3(nta)]center dot h2o 1, (nh4)(4)[wo3(cit)]center dot 2 h2o 2 and k-2(nh4)(2)[w2o6(edta)]center dot 4h(2)o 3, respectively. these three complexes have been characterized by ir, xps, tga-dta, h-1 and c-13 nmr spectroscopy. and their structures have been determined by x-ray crystallographic studies, which confirm that i and 2 are mononuclear compounds and 3 is a binuclear compound. each tungsten atom in 1-3 is coordinated to three unshared oxygen atoms, which adopt fac stereochemistry, while the remaining fac positions are occupied by three atoms from the ligands. the electrochemical properties of 2 and 3 have been investigated. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000245732800017 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/14595]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li DM,Cui LF,Xing YH,et al. Synthesis and structural characterization of new tungsten(VI) complexes with polycarboxylate ligands[J]. journal of molecular structure,2007,832(1-3):138-145. |
| APA | Li DM.,Cui LF.,Xing YH.,Xu JQ.,Yu JH.,...&Hu NH.(2007).Synthesis and structural characterization of new tungsten(VI) complexes with polycarboxylate ligands.journal of molecular structure,832(1-3),138-145. |
| MLA | Li DM,et al."Synthesis and structural characterization of new tungsten(VI) complexes with polycarboxylate ligands".journal of molecular structure 832.1-3(2007):138-145. |
入库方式： OAI收割
来源：长春应用化学研究所
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