Interfacial supramolecular self-assembled monolayers of C-60 by thiolated beta-cyclodextrin on gold surfaces via monoanionic C-60
文献类型：期刊论文
| 作者 | Liu W ; Zhang Y ; Gao X |
| 刊名 | journal of the american chemical society
 |
| 出版日期 | 2007 |
| 卷号 | 129期号:16页码:4973-4980 |
| 关键词 | EFFICIENT PHOTOCURRENT GENERATION PHOTOINDUCED ELECTRON-TRANSFER DONOR-ACCEPTOR HETEROJUNCTIONS QUARTZ-CRYSTAL MICROBALANCE HOST-GUEST INTERACTIONS GAMMA-CYCLODEXTRIN CHARGE-TRANSFER THIN-FILMS NONCOVALENT IMMOBILIZATION 2ND-HARMONIC GENERATION |
| ISSN号 | 0002-7863 |
| 通讯作者 | gao x |
| 中文摘要 | the supramolecular self-assembled monolayers (sams) of c-60 by thiolated beta-cyclodextrin (cd) on gold surfaces were constructed for the first time using c-60 monoanion. the results indicate that monoanionic c-60 plays a crucial role in the formation of the c-60-containing self-assembled monolayers. the generation of c-60 monoanion and the formation process of c-60 sams were monitored in-situ by uv-visible and near-ir spectroscopy. the resulting c-60 sams were fully characterized by spectroscopic ellipsometry (se), cyclic voltammetry, x-ray photoelectron spectroscopy (xps), and water contact angle measurements. after the immobilization of c-60 by the sams of thiolated beta-cd, the film thickness increased by approximately 1 nm from 0.8 to 1.8 nm as determined by se, demonstrating the formation of the supramolecular self-assembled monolayers of thiolated beta-cd/c-60. the new c-60 sams exhibited one quasi-reversible redox couple at half wave potential of -0.57 v vs sce in aqueous solution containing 0.1 m kcl. the surface coverage of c-60 on the gold surfaces was estimated to be 1.1 x 10(-10) mol cm(-2). the xps showed the assembly of c-60 over the thiolated beta-cd sams. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000245782800034 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/14631]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu W,Zhang Y,Gao X. Interfacial supramolecular self-assembled monolayers of C-60 by thiolated beta-cyclodextrin on gold surfaces via monoanionic C-60[J]. journal of the american chemical society,2007,129(16):4973-4980. |
| APA | Liu W,Zhang Y,&Gao X.(2007).Interfacial supramolecular self-assembled monolayers of C-60 by thiolated beta-cyclodextrin on gold surfaces via monoanionic C-60.journal of the american chemical society,129(16),4973-4980. |
| MLA | Liu W,et al."Interfacial supramolecular self-assembled monolayers of C-60 by thiolated beta-cyclodextrin on gold surfaces via monoanionic C-60".journal of the american chemical society 129.16(2007):4973-4980. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。