Electrocatalytic reduction of 1,2-diiodoethane by anions of supramolecular complex of (beta-CD)(2)/C-60 in DMF solution
文献类型：期刊论文
| 作者 | Ye D ; Zhang Y ; Gao X |
| 刊名 | electrochimica acta
 |
| 出版日期 | 2007 |
| 卷号 | 52期号:24页码:6686-6691 |
| 关键词 | GAMMA-CYCLODEXTRIN ELECTROCHEMICAL REDUCTION INCLUSION COMPLEXES NITRITE REDUCTASE BETA-CYCLODEXTRIN ELECTRON-TRANSFER C-60 WATER FULLERENES CHEMISTRY |
| ISSN号 | 0013-4686 |
| 通讯作者 | gao x |
| 中文摘要 | the homogeneous electrocatalytic reduction of 1,2-diiodoethane by anions of the supramolecular complex of (beta-cd)(2)/c-60 in dmf solution is reported. the results show that the trianion of (beta-cd)(2)/c-60 exhibits electrocatalytic behavior towards the reduction of 1,2-diiodoethane, whereas the diani on is unable to reduce the diiodoethane. the second-order catalytic rate constant in dmf solution was determined to be 3.1 x 10(5) m-1 s(-1) by analysis of voltammetric responses under pseudo-first-order conditions with respect to (beta-cd)(2)/c-60. the results suggest that the host beta-cyclodextrin molecules have little effect on the electrocatalytic ability of the encapsulated c-60 toward organic halides. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000248783300013 |
| 公开日期 | 2010-07-13 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/14635]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ye D,Zhang Y,Gao X. Electrocatalytic reduction of 1,2-diiodoethane by anions of supramolecular complex of (beta-CD)(2)/C-60 in DMF solution[J]. electrochimica acta,2007,52(24):6686-6691. |
| APA | Ye D,Zhang Y,&Gao X.(2007).Electrocatalytic reduction of 1,2-diiodoethane by anions of supramolecular complex of (beta-CD)(2)/C-60 in DMF solution.electrochimica acta,52(24),6686-6691. |
| MLA | Ye D,et al."Electrocatalytic reduction of 1,2-diiodoethane by anions of supramolecular complex of (beta-CD)(2)/C-60 in DMF solution".electrochimica acta 52.24(2007):6686-6691. |
入库方式： OAI收割
来源：长春应用化学研究所
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