中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Influences of catalysis and dispersion of organically modified montmorillonite on flame retardancy of polypropylene nanocomposites

文献类型:期刊论文

作者Song RJ ; Wang Z ; Meng XY ; Zhang BY ; Tang T
刊名journal of applied polymer science
出版日期2007
卷号106期号:5页码:3488-3494
关键词LAYERED-SILICATE NANOCOMPOSITES POLYMER/CLAY NANOCOMPOSITES THERMAL-DECOMPOSITION CRACKING CATALYST DEGRADATION MECHANISM CLAYS TRANSFORMATION HYDROCARBONS POLYOLEFINS
ISSN号0021-8995
通讯作者tang t
中文摘要the degradation and flame retardancy of polypropylene/organically modified montmorillonite (pp/ommt) nanocomposite were studied by means of gas chromatography-mass spectrometry and cone calorimeter. the catalysis of hydrogen proton containing montmorillonite (h-mmt) derived from thermal decomposition of (alkyl) ammonium in the ommt on degradation of pp strongly influence carbonization behavior of pp and then flame retardancy. bronsted acid sites on the h-mmt could catalyze degradation reaction of pp via cationic mechanism, which leads to the formation of char during combustion of pp via hydride transfer reaction. a continuous carbonaceous mmt-rich char on the surface of the burned residues, which work as a protective barrier to heat and mass transfer, results from the homogeneous dispersion of ommt in the pp matrix and appropriate char produced.
收录类别SCI
语种英语
WOS记录号WOS:000250410500082
公开日期2010-07-13
源URL[http://ir.ciac.jl.cn/handle/322003/14675]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Song RJ,Wang Z,Meng XY,et al. Influences of catalysis and dispersion of organically modified montmorillonite on flame retardancy of polypropylene nanocomposites[J]. journal of applied polymer science,2007,106(5):3488-3494.
APA Song RJ,Wang Z,Meng XY,Zhang BY,&Tang T.(2007).Influences of catalysis and dispersion of organically modified montmorillonite on flame retardancy of polypropylene nanocomposites.journal of applied polymer science,106(5),3488-3494.
MLA Song RJ,et al."Influences of catalysis and dispersion of organically modified montmorillonite on flame retardancy of polypropylene nanocomposites".journal of applied polymer science 106.5(2007):3488-3494.

入库方式: OAI收割

来源:长春应用化学研究所

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