Polyelectrolyte complexes basedon chitosan and poly(L-glutamic acid)
文献类型:期刊论文
作者 | Dai ZZ ; Yin JB ; Yan SF ; Cao T ; Ma J ; Chen XS |
刊名 | polymer international
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出版日期 | 2007 |
卷号 | 56页码:1122-1127 |
关键词 | CHITOSAN POLY(L-GLUTAMIC ACID) POLYELECTROLYTE COMPLEX INTERACTION MECHANISM SWELLING BEHAVIOR |
通讯作者 | chen xs |
中文摘要 | polyelectrolyte complexes (pecs) were prepared by mixing aqueous solutions of chitosan (cs) and poly(l-glutamic acid) (plga) at various ph. it was found that the stoichiometry of the pecs depends on ph.an investigation of the pecs using fourier transform infrared spectroscopy proved that the formation of the complexes is due to electrostatic interaction between –nh3 + groups of cs and –coo− groups of plga. the solid pecs were characterized using wide-angle x-ray diffraction, which suggested that a strong interaction occurs between the two polymers at ph = 4 or 5 and relatively weak interaction at ph = 3. these results were further confirmed by thermogravimetric analysis data. transmission electron microscopy showed that the complexes have a spherical shape. the effect of ionic strength on the size of the pecs was also studied using dynamic light scattering. it was found that the size of the pecs is dependent on ph. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2010-07-13 ; 2011-06-09 |
源URL | [http://ir.ciac.jl.cn/handle/322003/14693] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Dai ZZ,Yin JB,Yan SF,et al. Polyelectrolyte complexes basedon chitosan and poly(L-glutamic acid)[J]. polymer international,2007,56:1122-1127. |
APA | Dai ZZ,Yin JB,Yan SF,Cao T,Ma J,&Chen XS.(2007).Polyelectrolyte complexes basedon chitosan and poly(L-glutamic acid).polymer international,56,1122-1127. |
MLA | Dai ZZ,et al."Polyelectrolyte complexes basedon chitosan and poly(L-glutamic acid)".polymer international 56(2007):1122-1127. |
入库方式: OAI收割
来源:长春应用化学研究所
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