Determination of reserpine in urine by capillary electrophoresis with electrochemiluminescence detection
文献类型：期刊论文
| 作者 | Cao WD ; Yang XR ; Wang EK |
| 刊名 | electroanalysis
 |
| 出版日期 | 2004 |
| 卷号 | 16期号:3页码:169-174 |
| 关键词 | RU(BPY)(3)(3+)-BASED CHEMILUMINESCENCE DETECTION ELECTROGENERATED CHEMILUMINESCENCE FLOW-INJECTION AMINO-ACIDS CHROMATOGRAPHY ELECTRODE OXIDATION PEPTIDES SYSTEM |
| ISSN号 | 1040-0397 |
| 通讯作者 | yang xr |
| 中文摘要 | a fast and sensitive approach to detect reserpine in urine using micellar electrokinetic capillary chromatography with electrochemiluminescence (ecl) of ru(bpy)(3)(2+) detection is described. using a 25 mum i.d. capillary as separation column, the ecl detector was coupled to the capillary in the absence of an electric field decoupler. field-amplified injection was used to minimize the effect of ionic strength in the sample and to achieve high sensitivity. in this way, the sample was analyzed directly without any pretreatment. the method was validated for reserpine in the urine over the range of 1 x 10(-6) - 1 x 10(-4) mol/l with a correlation coefficient of 0.996. the rsd for reserpine at a level of 5 mumol/l was 4.3%. the lod (s/n = 3) was estimated to be 7.0 x 10(-8) mol/l. the average recoveries for 10 mumol/l reserpine spiked in human urine were 94%. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000220047100001 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/14833]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Cao WD,Yang XR,Wang EK. Determination of reserpine in urine by capillary electrophoresis with electrochemiluminescence detection[J]. electroanalysis,2004,16(3):169-174. |
| APA | Cao WD,Yang XR,&Wang EK.(2004).Determination of reserpine in urine by capillary electrophoresis with electrochemiluminescence detection.electroanalysis,16(3),169-174. |
| MLA | Cao WD,et al."Determination of reserpine in urine by capillary electrophoresis with electrochemiluminescence detection".electroanalysis 16.3(2004):169-174. |
入库方式： OAI收割
来源：长春应用化学研究所
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