Facilitated ion-transfer of sodium cation by (anthraquinone-1-yloxy) methane-15-crown-5 across the water/1,2-dichloroethane microinterface
文献类型：期刊论文
| 作者 | Han XJ ; Zhang ZQ ; Dong SJ ; Wang E |
| 刊名 | electroanalysis
 |
| 出版日期 | 2004 |
| 卷号 | 16期号:12页码:1014-1018 |
| 关键词 | IMMISCIBLE ELECTROLYTE-SOLUTIONS WATER-NITROBENZENE POTENTIAL WINDOW LIQUID INTERFACE MICRO-ITIES DIBENZO-18-CROWN-6 MICROPIPETTES VOLTAMMETRY KINETICS PHASE |
| ISSN号 | 1040-0397 |
| 通讯作者 | dong sj |
| 中文摘要 | the transfer of sodium cation facilitated by (anthraquinone-1-yloxy) methane-15-crown-5(l) has been investigated at the water/1,2-dichloroethane microinterface supported at the tip of a micropipette. the diffusion coefficient of (anthraquinone-1-yloxy) methane-15-crown-5 obtained was (3.42 +/- 0.20) x 10(-6) cm(2) s(-1). the steady-state voltammograms were observed for forward and backward scans due to sodium ion transfer facilitated by l with 1:1 stoichiometry. the mechanism corresponded to an interfacial complexation (tic) and interfacial dissociation (tid) process. the association constant was calculated to be log beta(o) = 11.08 +/- 0.03 in the dce phase. the association constant of other alkali metals (li+, k+, rb+) were also obtained. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000222397600007 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://202.98.16.49/handle/322003/14835]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Han XJ,Zhang ZQ,Dong SJ,et al. Facilitated ion-transfer of sodium cation by (anthraquinone-1-yloxy) methane-15-crown-5 across the water/1,2-dichloroethane microinterface[J]. electroanalysis,2004,16(12):1014-1018. |
| APA | Han XJ,Zhang ZQ,Dong SJ,&Wang E.(2004).Facilitated ion-transfer of sodium cation by (anthraquinone-1-yloxy) methane-15-crown-5 across the water/1,2-dichloroethane microinterface.electroanalysis,16(12),1014-1018. |
| MLA | Han XJ,et al."Facilitated ion-transfer of sodium cation by (anthraquinone-1-yloxy) methane-15-crown-5 across the water/1,2-dichloroethane microinterface".electroanalysis 16.12(2004):1014-1018. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。