Determination of benzhexol hydrochloride by capillary zone electrophoresis with an end-column electrochemiluminescence detection
文献类型：期刊论文
| 作者 | Yan JL ; Liu JF ; Cao WD ; Sun XH ; Yang XR ; Wang EK |
| 刊名 | microchemical journal
 |
| 出版日期 | 2004 |
| 卷号 | 76期号:1-2页码:11-16 |
| 关键词 | RU(BPY)(3)(3+)-BASED CHEMILUMINESCENCE DETECTION IONIZATION MASS-SPECTROMETRY ELECTROGENERATED CHEMILUMINESCENCE GAS-CHROMATOGRAPHY LIQUID-CHROMATOGRAPHY HUMAN SERUM TRIHEXYPHENIDYL DRUGS TRIS(2 PROCYCLIDINE 2'-BIPYRIDYL)RUTHENIUM(III) |
| ISSN号 | 0026-265x |
| 通讯作者 | wang ek |
| 中文摘要 | a capillary zone electrophoresis with end-column electrochemiluminescence (ecl) detector was described for the determination of benzhexol hydrochloride. the detection was based on the tris(2,2'-bypyridine)ruthenium(ii) [ru(bpy)(3)(2+)] ecl reaction with the analyte. electrophoresis was performed using a 25 mum i.d. uncoated capillary. 10 mm sodium phosphate buffer (ph=8.0) was used as the running buffer. the solution in the detection cell was 80 mm sodium phosphate (ph=8.0) and 5 mm)21 ru(bpy)(3)(2+). a linear calibration curve of three-orders of magnitude was obtained (with a correlation coefficient of > 0.999) from 1.0x10(-8) to 1.0x10(-5) m and the limit of detection was 6.7 x 10(-9) m (s/n= 3). this just provides an easy and sensitive method to determine the active ingredient in pharmaceutical formulations. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000220857500002 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://202.98.16.49/handle/322003/14839]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yan JL,Liu JF,Cao WD,et al. Determination of benzhexol hydrochloride by capillary zone electrophoresis with an end-column electrochemiluminescence detection[J]. microchemical journal,2004,76(1-2):11-16. |
| APA | Yan JL,Liu JF,Cao WD,Sun XH,Yang XR,&Wang EK.(2004).Determination of benzhexol hydrochloride by capillary zone electrophoresis with an end-column electrochemiluminescence detection.microchemical journal,76(1-2),11-16. |
| MLA | Yan JL,et al."Determination of benzhexol hydrochloride by capillary zone electrophoresis with an end-column electrochemiluminescence detection".microchemical journal 76.1-2(2004):11-16. |
入库方式： OAI收割
来源：长春应用化学研究所
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