Structure characterization and physical properties of a complex with supramolecular architectures Co-2(2,6-DPC2Co(H2O)5 center dot 2H(2)O (DPC=2,6-pyridinedicarboxylate)
文献类型：期刊论文
| 作者 | Qi YJ ; Wang YH ; Fan HL ; Cao MH ; Mao L ; Hu CW ; Wang E ; Hu NH |
| 刊名 | journal of molecular structure
 |
| 出版日期 | 2004 |
| 卷号 | 694期号:1-3页码:73-78 |
| 关键词 | HYDROTHERMAL SYNTHESIS COORDINATION NETWORKS POLYMER NI CO 3 CADMIUM(II) FRAMEWORKS PDC ZN 5-PYRIDINEDICARBOXYLATE |
| ISSN号 | 0022-2860 |
| 通讯作者 | qi yj |
| 中文摘要 | reaction of 2,6-pyridinedicarboxylic with cocl2 . 6h(2)o in aqueous solution give rise to a three-dimensional complex co2(2,6-dpc)(2)co(h2o)(5).2h(2)o (dpc = 2,6-pyridinedicarboxylate) 1. it has been characterized by elemental analyses, infrared spectra (ir) spectrum, thermogravimetric (tg) analysis, epr spectrum, and single crystal x-ray diffraction. the complex crystallizes in the p2(1)/c space group with a = 8.3906(3) angstrom, b = 27.4005(8) angstrom, c = 9.6192(4) a, alpha = 90.00degrees, beta = 98.327(2)degrees, gamma = 90.00degrees, v = 2188.20(14) angstrom(3), z = 4. there are two types of cobalt environments: co(1) is coordinated by four oxygen atoms from four carboxyl groups and two nitrogen 2 atoms which are all from pdc(2). co(2) is coordinated by six oxygen atoms, five from coordinated water molecules and one from a carboxyl of pdc(2) - of which the other oxygen atom is linked to the co(1). the extensive intermolecular hydrogen bonds are formed in the crystal by means of the five coordinated water molecules. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000221656500009 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://202.98.16.49/handle/322003/14905]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qi YJ,Wang YH,Fan HL,et al. Structure characterization and physical properties of a complex with supramolecular architectures Co-2(2,6-DPC2Co(H2O)5 center dot 2H(2)O (DPC=2,6-pyridinedicarboxylate)[J]. journal of molecular structure,2004,694(1-3):73-78. |
| APA | Qi YJ.,Wang YH.,Fan HL.,Cao MH.,Mao L.,...&Hu NH.(2004).Structure characterization and physical properties of a complex with supramolecular architectures Co-2(2,6-DPC2Co(H2O)5 center dot 2H(2)O (DPC=2,6-pyridinedicarboxylate).journal of molecular structure,694(1-3),73-78. |
| MLA | Qi YJ,et al."Structure characterization and physical properties of a complex with supramolecular architectures Co-2(2,6-DPC2Co(H2O)5 center dot 2H(2)O (DPC=2,6-pyridinedicarboxylate)".journal of molecular structure 694.1-3(2004):73-78. |
入库方式： OAI收割
来源：长春应用化学研究所
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