Poly(vinylidene fluoride-hexafluoropropylene)/organo-montmorillonite clays nanocomposite lithium polymer electrolytes
文献类型:期刊论文
作者 | Wang MK ; Zhao F ; Guo ZH ; Dong SJ |
刊名 | electrochimica acta
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出版日期 | 2004 |
卷号 | 49期号:21页码:3595-3602 |
关键词 | ION BATTERIES VIBRATIONAL SPECTROSCOPY BLOCKING ELECTRODES GEL ELECTROLYTES CONDUCTIVITY MORPHOLOGY IMPEDANCE MICROELECTRODE SALTS |
ISSN号 | 0013-4686 |
通讯作者 | dong sj |
中文摘要 | polymer-clay nanocomposite (pcn) materials were prepared by intercalation of an alkyl-ammonium ion spacing/coupling agent and a polymer between the planar layers of a swellable-layered material, such as montmorillonite (mmt). the nanocomposite lithium polymer electrolytes comprising such pcn materials and/or a dielectric solution (propylene carbonate) were prepared and discussed. the chemical composition of the nanocomposite materials was determined with x-ray diffraction (xrd) and fourier transform infrared (ftir) spectroscopy, which revealed that the alkyl-ammonium ion successfully intercalated the layer of mmt clay, and thus copolymer poly(vinylidene fluoride-hexafluoropropylene) entered the galleries of montmorillonite clay. cyclic voltammetry and electrochemical impedance spectroscopy (eis) were used to investigate the electrochemical properties of the lithium polymer electrolyte. equivalent circuits were proposed to fit the eis data successfully, and the significant contribution from mmt was thus identified. the resulting polymer electrolytes show high ionic conductivity up to 10(-3) s cm(-1) after felling with propylene carbonate. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000222253700016 |
公开日期 | 2010-08-17 |
源URL | [http://202.98.16.49/handle/322003/14999] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Wang MK,Zhao F,Guo ZH,et al. Poly(vinylidene fluoride-hexafluoropropylene)/organo-montmorillonite clays nanocomposite lithium polymer electrolytes[J]. electrochimica acta,2004,49(21):3595-3602. |
APA | Wang MK,Zhao F,Guo ZH,&Dong SJ.(2004).Poly(vinylidene fluoride-hexafluoropropylene)/organo-montmorillonite clays nanocomposite lithium polymer electrolytes.electrochimica acta,49(21),3595-3602. |
MLA | Wang MK,et al."Poly(vinylidene fluoride-hexafluoropropylene)/organo-montmorillonite clays nanocomposite lithium polymer electrolytes".electrochimica acta 49.21(2004):3595-3602. |
入库方式: OAI收割
来源:长春应用化学研究所
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