中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Poly(vinylidene fluoride-hexafluoropropylene)/organo-montmorillonite clays nanocomposite lithium polymer electrolytes

文献类型:期刊论文

作者Wang MK ; Zhao F ; Guo ZH ; Dong SJ
刊名electrochimica acta
出版日期2004
卷号49期号:21页码:3595-3602
关键词ION BATTERIES VIBRATIONAL SPECTROSCOPY BLOCKING ELECTRODES GEL ELECTROLYTES CONDUCTIVITY MORPHOLOGY IMPEDANCE MICROELECTRODE SALTS
ISSN号0013-4686
通讯作者dong sj
中文摘要polymer-clay nanocomposite (pcn) materials were prepared by intercalation of an alkyl-ammonium ion spacing/coupling agent and a polymer between the planar layers of a swellable-layered material, such as montmorillonite (mmt). the nanocomposite lithium polymer electrolytes comprising such pcn materials and/or a dielectric solution (propylene carbonate) were prepared and discussed. the chemical composition of the nanocomposite materials was determined with x-ray diffraction (xrd) and fourier transform infrared (ftir) spectroscopy, which revealed that the alkyl-ammonium ion successfully intercalated the layer of mmt clay, and thus copolymer poly(vinylidene fluoride-hexafluoropropylene) entered the galleries of montmorillonite clay. cyclic voltammetry and electrochemical impedance spectroscopy (eis) were used to investigate the electrochemical properties of the lithium polymer electrolyte. equivalent circuits were proposed to fit the eis data successfully, and the significant contribution from mmt was thus identified. the resulting polymer electrolytes show high ionic conductivity up to 10(-3) s cm(-1) after felling with propylene carbonate.
收录类别SCI
语种英语
WOS记录号WOS:000222253700016
公开日期2010-08-17
源URL[http://202.98.16.49/handle/322003/14999]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Wang MK,Zhao F,Guo ZH,et al. Poly(vinylidene fluoride-hexafluoropropylene)/organo-montmorillonite clays nanocomposite lithium polymer electrolytes[J]. electrochimica acta,2004,49(21):3595-3602.
APA Wang MK,Zhao F,Guo ZH,&Dong SJ.(2004).Poly(vinylidene fluoride-hexafluoropropylene)/organo-montmorillonite clays nanocomposite lithium polymer electrolytes.electrochimica acta,49(21),3595-3602.
MLA Wang MK,et al."Poly(vinylidene fluoride-hexafluoropropylene)/organo-montmorillonite clays nanocomposite lithium polymer electrolytes".electrochimica acta 49.21(2004):3595-3602.

入库方式: OAI收割

来源:长春应用化学研究所

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