Synthesis, crystal structure, and thermal property of a novel supramolecular assembly: (NH42810424)(CHNO) O-[H(V)O(]2H)4(10)28(2), constructed from decavanadate and caffeine
文献类型：期刊论文
| 作者 | Zhai HJ ; Liu SX ; Peng J ; Hu NH ; Jia HQ |
| 刊名 | journal of chemical crystallography
 |
| 出版日期 | 2004 |
| 卷号 | 34期号:8页码:541-548 |
| ISSN号 | 1074-1542 |
| 关键词 | BINDING SITES |
| 通讯作者 | liu sx |
| 中文摘要 | a novel 3d supramolecular assembly constructed from decavanadate and caffeine building blocks, (nh4)(2)(c8h10n4o2)(4)[h4v10o28].2h(2)o (1), has been synthesized in aqueous solution and characterized by elemental analysis, ir, h-1 nmr, v-51 nmr, tg-dta, and single crystal x-ray diffraction. the compound 1 crystallizes in monoclinic system, space group p2(1)/n, a = 15.801(1) angstrom, b = 12.914(1) angstrom, c = 15.913(2) angstrom, beta = 113.55degrees, v = 2976.4 (5) angstrom(3), z = 2, r = 0.0498 with 6818 reflections. water molecules, ammonium ions, and caffeine act as "cement" linking the polyanions into 1d chain along the c-axis by hydrogen bonding. in compound 1, extensive hydrogen-bond contacts and strong pi-pi interactions lead to an ordered 3d supramolecular framework. tg-dta curves indicate that the weight loss of the complex can be divided into three stages. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000223916500009 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://202.98.16.49/handle/322003/15039]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhai HJ,Liu SX,Peng J,et al. Synthesis, crystal structure, and thermal property of a novel supramolecular assembly: (NH42810424)(CHNO) O-[H(V)O(]2H)4(10)28(2), constructed from decavanadate and caffeine[J]. journal of chemical crystallography,2004,34(8):541-548. |
| APA | Zhai HJ,Liu SX,Peng J,Hu NH,&Jia HQ.(2004).Synthesis, crystal structure, and thermal property of a novel supramolecular assembly: (NH42810424)(CHNO) O-[H(V)O(]2H)4(10)28(2), constructed from decavanadate and caffeine.journal of chemical crystallography,34(8),541-548. |
| MLA | Zhai HJ,et al."Synthesis, crystal structure, and thermal property of a novel supramolecular assembly: (NH42810424)(CHNO) O-[H(V)O(]2H)4(10)28(2), constructed from decavanadate and caffeine".journal of chemical crystallography 34.8(2004):541-548. |
入库方式： OAI收割
来源：长春应用化学研究所
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