Structure and liquid crystalline properties of 5-[(4 '-heptoxy-4-biphenylyl)carbonyloxy]-1-pentyne
文献类型:期刊论文
作者 | Geng JX ; Wang SY ; Ling W ; Li G ; Zhou EL ; Lam JWY ; Tang BZ |
刊名 | liquid crystals
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出版日期 | 2004 |
卷号 | 31期号:1页码:71-79 |
关键词 | POLYACETYLENES DERIVATIVES POLYTHIOPHENE |
ISSN号 | 0267-8292 |
通讯作者 | zhou el |
中文摘要 | the crystal structure and liquid crystalline properties of a biphenyl-containing acetylene, [5-[(4'-heptoxy-4- biphenylyl) carbonyloxy]-1-pentyne (a3eo7) were investigated by electron crystallography, x-ray diffraction, polarizing optical microscopy, differential scanning calorimetry, transmission electron microscopy, and atomic force microscopy. a3eo7 crystals obtained from a toluene solution adopts a monoclinic p112/m space group with unit cell parameters of a = 6.25 angstrom, b = 7.82 angstrom, c = 46.70 angstrom and gamma = 96.7degrees, as determined using electron diffraction. upon cooling from the isotropic phase, a3eo7 exhibits a smectic a phase in the temperature range 72.4 - 53.6degreesc. further lowering of the temperature results in the formation of a smectic c phase which exhibits a strong tendency towards crystallization. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000187560500008 |
公开日期 | 2010-08-17 |
源URL | [http://ir.ciac.jl.cn/handle/322003/15101] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Geng JX,Wang SY,Ling W,et al. Structure and liquid crystalline properties of 5-[(4 '-heptoxy-4-biphenylyl)carbonyloxy]-1-pentyne[J]. liquid crystals,2004,31(1):71-79. |
APA | Geng JX.,Wang SY.,Ling W.,Li G.,Zhou EL.,...&Tang BZ.(2004).Structure and liquid crystalline properties of 5-[(4 '-heptoxy-4-biphenylyl)carbonyloxy]-1-pentyne.liquid crystals,31(1),71-79. |
MLA | Geng JX,et al."Structure and liquid crystalline properties of 5-[(4 '-heptoxy-4-biphenylyl)carbonyloxy]-1-pentyne".liquid crystals 31.1(2004):71-79. |
入库方式: OAI收割
来源:长春应用化学研究所
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