Enantioselective iodolactonization catalyzed by chiral quaternary ammonium salts derived from cinchonidine
文献类型:期刊论文
作者 | Wang M ; Gao LX ; Mai WP ; Xia AX ; Wang F ; Zhang SB |
刊名 | journal of organic chemistry
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出版日期 | 2004 |
卷号 | 69期号:8页码:2874-2876 |
关键词 | AUXILIARY PHASE 3 HALOCYCLIZATION AMIDES 5-DISUBSTITUTED-GAMMA-BUTYROLACTONES |
ISSN号 | 0022-3263 |
通讯作者 | gao lx |
中文摘要 | chiral quaternary ammonium salts derived from cinchonidine have been applied to catalyze the stereoselective iodolactonizations of trans-5-aryl-4-pentenoic acids leading to a mixture of two regioselectively iodolactonized products with fair to excellent yield (37-98%) and moderate enantioselectivity (exo = 42.0% ee, endo = 31.0% ee) under mild conditions. this work is the first example of asymmetric iodolactonization reaction in the presence of less than a stoichiometric amount of chiral reagent. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000220752500035 |
公开日期 | 2010-08-17 |
源URL | [http://202.98.16.49/handle/322003/15139] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Wang M,Gao LX,Mai WP,et al. Enantioselective iodolactonization catalyzed by chiral quaternary ammonium salts derived from cinchonidine[J]. journal of organic chemistry,2004,69(8):2874-2876. |
APA | Wang M,Gao LX,Mai WP,Xia AX,Wang F,&Zhang SB.(2004).Enantioselective iodolactonization catalyzed by chiral quaternary ammonium salts derived from cinchonidine.journal of organic chemistry,69(8),2874-2876. |
MLA | Wang M,et al."Enantioselective iodolactonization catalyzed by chiral quaternary ammonium salts derived from cinchonidine".journal of organic chemistry 69.8(2004):2874-2876. |
入库方式: OAI收割
来源:长春应用化学研究所
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