Synthesis, structure and norbornene polymerization behavior of nickel complexes bearing two beta-ketoiminato chelate ligands
文献类型：期刊论文
| 作者 | Zhu YZ ; Liu JY ; Li YS ; Tong YJ |
| 刊名 | journal of organometallic chemistry
 |
| 出版日期 | 2004 |
| 卷号 | 689期号:7页码:1295-1303 |
| 关键词 | VINYL-TYPE POLYMERIZATION ADDITION POLYMERIZATION PALLADIUM(II) COMPLEXES ALUMINOXANE CATALYSTS COPOLYMERIZATION POLYNORBORNENE HOMOPOLYMERIZATION ETHYLENE ETHENE METHYLALUMINOXANE |
| ISSN号 | 0022-328x |
| 通讯作者 | li ys |
| 中文摘要 | a series of nickel(ii) complexes bearing two nonsymmetric bidentate beta-ketoiminato chelate ligands have been prepared, and the structures of complexes [(2,6-me2c6h3)nc(ch3)c(h)c(ph)o](2)ni (4a) and [(2,6-me2c6h3)nc(ch3)c(h)c(cf3)o](2)ni (4c) have been confirmed by x-ray crystallographic analysis. these nickel(ii) complexes were investigated as catalysts for the vinylic polymerization of norbornene. using modified methylaluminoxane (mmao) as a cocatalyst, these complexes display very high activities and produce high molecular weight polymers. catalytic activity of up to 1.16 x 10(4) kg/mol(ni) .h and the viscosity-average molecular 9 weight of polymer of up to 870 kg/mol were observed. catalyst activity, polymer yield, and polymer molecular weight could be controlled over a wide range by the variation of the reaction parameters such as al/ni molar ratio, norbornene/catalyst molar ratio, monomer concentration, polymerization reaction temperature and time. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000220549200026 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://202.98.16.49/handle/322003/15293]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhu YZ,Liu JY,Li YS,et al. Synthesis, structure and norbornene polymerization behavior of nickel complexes bearing two beta-ketoiminato chelate ligands[J]. journal of organometallic chemistry,2004,689(7):1295-1303. |
| APA | Zhu YZ,Liu JY,Li YS,&Tong YJ.(2004).Synthesis, structure and norbornene polymerization behavior of nickel complexes bearing two beta-ketoiminato chelate ligands.journal of organometallic chemistry,689(7),1295-1303. |
| MLA | Zhu YZ,et al."Synthesis, structure and norbornene polymerization behavior of nickel complexes bearing two beta-ketoiminato chelate ligands".journal of organometallic chemistry 689.7(2004):1295-1303. |
入库方式： OAI收割
来源：长春应用化学研究所
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