中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis, structure and norbornene polymerization behavior of neutral palladium complexes

文献类型:期刊论文

作者Liang H ; Liu JY ; Li XF ; Li YS
刊名polyhedron
出版日期2004
卷号23期号:9页码:1619-1627
关键词VINYL-TYPE POLYMERIZATION NICKEL(II)-BASED CATALYSTS ALUMINOXANE CATALYSTS METAL-CATALYSTS COPOLYMERIZATION ETHYLENE LIGANDS HOMOPOLYMERIZATION POLYNORBORNENES ETHENE
ISSN号0277-5387
通讯作者li ys
中文摘要a series of neutral palladium(ii) complexes bearing non-symmetric bidentate pyrrole-iminato or salicylaldiminato chelate ligands have been synthesized, and the structure of representative complexes (3a, 4a, and 5a) have been confirmed by x-ray crystallographic analysis. these palladium complexes have been investigated as catalysts for the polymerization of norbornene. using modified methylaluminoxane (mmao) as a cocatalyst, these complexes display high activities and produce vinyl-addition polynorborenes. catalytic activity of up to 8.52 x 10(3) kg/mol(pd) h has been observed. wide-angle x-ray diffraction (waxd) has been used to investigate the polymer microstructure and it has been found that they are non-crystalline.
收录类别SCI
语种英语
WOS记录号WOS:000221778800016
公开日期2010-08-17
源URL[http://ir.ciac.jl.cn/handle/322003/15295]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Liang H,Liu JY,Li XF,et al. Synthesis, structure and norbornene polymerization behavior of neutral palladium complexes[J]. polyhedron,2004,23(9):1619-1627.
APA Liang H,Liu JY,Li XF,&Li YS.(2004).Synthesis, structure and norbornene polymerization behavior of neutral palladium complexes.polyhedron,23(9),1619-1627.
MLA Liang H,et al."Synthesis, structure and norbornene polymerization behavior of neutral palladium complexes".polyhedron 23.9(2004):1619-1627.

入库方式: OAI收割

来源:长春应用化学研究所

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