Synthesis, structure and norbornene polymerization behavior of neutral palladium complexes
文献类型:期刊论文
作者 | Liang H ; Liu JY ; Li XF ; Li YS |
刊名 | polyhedron
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出版日期 | 2004 |
卷号 | 23期号:9页码:1619-1627 |
关键词 | VINYL-TYPE POLYMERIZATION NICKEL(II)-BASED CATALYSTS ALUMINOXANE CATALYSTS METAL-CATALYSTS COPOLYMERIZATION ETHYLENE LIGANDS HOMOPOLYMERIZATION POLYNORBORNENES ETHENE |
ISSN号 | 0277-5387 |
通讯作者 | li ys |
中文摘要 | a series of neutral palladium(ii) complexes bearing non-symmetric bidentate pyrrole-iminato or salicylaldiminato chelate ligands have been synthesized, and the structure of representative complexes (3a, 4a, and 5a) have been confirmed by x-ray crystallographic analysis. these palladium complexes have been investigated as catalysts for the polymerization of norbornene. using modified methylaluminoxane (mmao) as a cocatalyst, these complexes display high activities and produce vinyl-addition polynorborenes. catalytic activity of up to 8.52 x 10(3) kg/mol(pd) h has been observed. wide-angle x-ray diffraction (waxd) has been used to investigate the polymer microstructure and it has been found that they are non-crystalline. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000221778800016 |
公开日期 | 2010-08-17 |
源URL | [http://ir.ciac.jl.cn/handle/322003/15295] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Liang H,Liu JY,Li XF,et al. Synthesis, structure and norbornene polymerization behavior of neutral palladium complexes[J]. polyhedron,2004,23(9):1619-1627. |
APA | Liang H,Liu JY,Li XF,&Li YS.(2004).Synthesis, structure and norbornene polymerization behavior of neutral palladium complexes.polyhedron,23(9),1619-1627. |
MLA | Liang H,et al."Synthesis, structure and norbornene polymerization behavior of neutral palladium complexes".polyhedron 23.9(2004):1619-1627. |
入库方式: OAI收割
来源:长春应用化学研究所
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