Stable ordered mesoporous silica materials templated by high-temperature stable surfactant micelle in alkaline media
文献类型：期刊论文
| 作者 | Yang XY ; Zhang SB ; Qiu ZM ; Tian G ; Feng YF ; Xiao FS |
| 刊名 | journal of physical chemistry b
 |
| 出版日期 | 2004 |
| 卷号 | 108期号:15页码:4696-4700 |
| 关键词 | MOLECULAR-SIEVES TRIBLOCK COPOLYMER ACIDIC MEDIA ALUMINOSILICATES STABILITY MCM-41 NETWORK SEEDS |
| ISSN号 | 1520-6106 |
| 通讯作者 | xiao fs |
| 中文摘要 | ordered hexagonal mesoporous silica material (jlu-30) has been successfully synthesized in alkaline media at high temperature (> 160 degreesc, using cationic (1,3-dimethyl-2-imidazolidin-2-ylidene)hexadecylmethyl-ammonium bromide (dihab) as a template, and characterized with x-ray diffraction (xrd), transmission electron microscopy (tem), nitrogen adsorption-desorption isotherms, differential thermal analysis (dta), and thermogravimetric analysis (tg), as well as al-27 and si-29 nuclear magnetic resonance (nmr) spectroscopy. mesoporous jlu-30 shows much higher hydrothermal stability than mcm-41. si-29 nmr spectra indicate that the pore walls of jlu-30 samples synthesized at high temperature (160 degreesc) are fully condensed, giving a q(4)/q(3) ratio as high as 6.2. in contrast, mcm-41 synthesized at relatively low temperature (100 degreesc) shows the q(4)/q(3) + q(2) ratio at 1.1. such unique structural feature might be responsible for the observed highly hydrothermal stability of the mesoporous silica materials (jlu-30). |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000220724700022 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://202.98.16.49/handle/322003/15313]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yang XY,Zhang SB,Qiu ZM,et al. Stable ordered mesoporous silica materials templated by high-temperature stable surfactant micelle in alkaline media[J]. journal of physical chemistry b,2004,108(15):4696-4700. |
| APA | Yang XY,Zhang SB,Qiu ZM,Tian G,Feng YF,&Xiao FS.(2004).Stable ordered mesoporous silica materials templated by high-temperature stable surfactant micelle in alkaline media.journal of physical chemistry b,108(15),4696-4700. |
| MLA | Yang XY,et al."Stable ordered mesoporous silica materials templated by high-temperature stable surfactant micelle in alkaline media".journal of physical chemistry b 108.15(2004):4696-4700. |
入库方式： OAI收割
来源：长春应用化学研究所
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