Grafting of maleic anhydride onto linear polyethylene: A Monte Carlo study
文献类型：期刊论文
| 作者 | Zhu YT ; Zhang RH ; Wei JA |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2004 |
| 卷号 | 42期号:22页码:5714-5724 |
| 关键词 | MOLECULAR-WEIGHT DISTRIBUTION CROSS-LINKING COPOLYMERIZATION FREE-RADICAL POLYMERIZATION REACTIVE EXTRUSION NETWORK FORMATION SIMULATION NMR POLYPROPYLENE KINETICS DISTRIBUTIONS |
| ISSN号 | 0887-624x |
| 通讯作者 | wei ja |
| 中文摘要 | monte carlo simulation was used to study the graft of maleic anhydride (mah) onto linear polyethylene (pe-g-mah) initiated by dicumyl peroxide (dcp). simulation results revealed that major mah monomers attached onto pe chains as branched graft at higher mah content. however, at extremely low mah content, the fraction of bridged graft was very close to that of branched graft. this conclusion was somewhat different from the conventional viewpoint, namely, the fraction of bridged graft was always much lower than that of branched graft under any condition. moreover, the results indicated that the grafting degree increased almost linearly to mah and dcp concentrations. on the other hand, it was found that the amount of grafted mah dropped sharply with increasing the length of grafted mah, indicating that mah monomers were mainly attached onto the pe chain as single mah groups or very short oligomers. with respect to the crosslink of pe, the results showed that the fraction of pe-(mah)(n)-pe crosslink structure increased continuously, and hence the fraction of pe-pe crosslink decreased with increasing mah concentration. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000224810000016 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://202.98.16.49/handle/322003/15329]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhu YT,Zhang RH,Wei JA. Grafting of maleic anhydride onto linear polyethylene: A Monte Carlo study[J]. journal of polymer science part a-polymer chemistry,2004,42(22):5714-5724. |
| APA | Zhu YT,Zhang RH,&Wei JA.(2004).Grafting of maleic anhydride onto linear polyethylene: A Monte Carlo study.journal of polymer science part a-polymer chemistry,42(22),5714-5724. |
| MLA | Zhu YT,et al."Grafting of maleic anhydride onto linear polyethylene: A Monte Carlo study".journal of polymer science part a-polymer chemistry 42.22(2004):5714-5724. |
入库方式： OAI收割
来源：长春应用化学研究所
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