Syntheses and crystal structures of [Mn(H2O)(4)(bpy)]L center dot 4H(2)O, [Mn(H2O)(4)(bpy)]L ' center dot 4H(2)O (H2L = SUCCINIC ACID, H2L ' = FUMARIC ACID)
文献类型：期刊论文
| 作者 | Ying EB ; Zheng YQ ; Zhang HJ |
| 刊名 | journal of coordination chemistry
 |
| 出版日期 | 2004 |
| 卷号 | 57期号:6页码:459-467 |
| 关键词 | METAL-ORGANIC FRAMEWORK COORDINATION POLYMERS TRANSFORMATION STORAGE DESIGN LIGAND SOLIDS PORES |
| ISSN号 | 0095-8972 |
| 通讯作者 | zhang hj |
| 中文摘要 | reactions of freshly prepared m(oh)(2-2x)(co3)(x) (.) yh(2)o (m = mn, zn) and 4,4'-bipyridine (bpy) with succinic acid (h2l) or famaric acid (h2l') in ch3oh-h2o afforded [mn(h2o)(4)(bpy)]l (.) 4h(2)o, 1, [mn(h2o)(4)(bpy)]l' (.) 4h(2)o, 2 and [zn(h2o)(4)(bpy)]l (.) 4h(2)o, 3. the three coordination polymers are isostructural and consist of (1)(infinity)[m(h2o)(4)(bpy)(2/2)](2+) cationic chains, crystal h2o molecules and dicarboxylate anions (succinate or fumarate anions). within the chains, the metal atoms are each octahedrally coordinated by four aqua oxygen atoms and two pyridyl nitrogen atoms from two 4,4'-bipyridine ligands. the crystal h2o molecules are hydrogen bonded to dicarboxylate anions to form ribbon-like anionic chains. the cationic and anionic chains are interconnected via hyqrogen bonds to generate a 3d network. crystal data: 1 triclinic, p (1) over bar, a = 7.235(1), b = 7.749(2), c = 10.020(2) angstrom, alpha = 79.95(3), beta = 88.79(3), gamma = 71.39(3)degrees, v = 523.9(2) angstrom(3) and d-cal = 1.494 g cm(-3) for z = 1; 2 triclinic, p (1) over bar, a = 7.127(1), b = 7.800(2), c = 9.945(2) angstrom, alpha = 80.26(3), beta = 87.86(3), gamma = 72.69(3)degrees, v = 520.2(2) angstrom(3) and d-cal = 1.498 g cm(-3) for z = 1; 3 triclinic, p (1) over bar, a = 7.189(1), b = 7.764(2), c = 9.843(2) angstrom, alpha = 79.16(3), beta = 87.80(3), gamma = 71.29(3)degrees, v = 510.9(2) angstrom(3) and d-cal = 1.559 g cm(-3) for z = 1. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000222750200003 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://202.98.16.49/handle/322003/15543]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ying EB,Zheng YQ,Zhang HJ. Syntheses and crystal structures of [Mn(H2O)(4)(bpy)]L center dot 4H(2)O, [Mn(H2O)(4)(bpy)]L ' center dot 4H(2)O (H2L = SUCCINIC ACID, H2L ' = FUMARIC ACID)[J]. journal of coordination chemistry,2004,57(6):459-467. |
| APA | Ying EB,Zheng YQ,&Zhang HJ.(2004).Syntheses and crystal structures of [Mn(H2O)(4)(bpy)]L center dot 4H(2)O, [Mn(H2O)(4)(bpy)]L ' center dot 4H(2)O (H2L = SUCCINIC ACID, H2L ' = FUMARIC ACID).journal of coordination chemistry,57(6),459-467. |
| MLA | Ying EB,et al."Syntheses and crystal structures of [Mn(H2O)(4)(bpy)]L center dot 4H(2)O, [Mn(H2O)(4)(bpy)]L ' center dot 4H(2)O (H2L = SUCCINIC ACID, H2L ' = FUMARIC ACID)".journal of coordination chemistry 57.6(2004):459-467. |
入库方式： OAI收割
来源：长春应用化学研究所
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