Syntheses, crystal structures and properties of two Cu(II) coordination polymers: Cu(C3N2H4)(2)(HL)(2) andCU(C3N2H4)(2)L with C3N2H4 = imidazole, H2L = adipic acid
文献类型：期刊论文
| 作者 | Ying EB ; Zheng YQ ; Zhang HH |
| 刊名 | journal of molecular structure
 |
| 出版日期 | 2004 |
| 卷号 | 693期号:1-3页码:73-80 |
| 关键词 | PI STACKING INTERACTIONS MAGNETIC-PROPERTIES MANGANESE(II) COMPLEXES HYDROTHERMAL SYNTHESIS ODAH(2)=OCTANEDIOIC ACID COBALT(II) CARBOXYLATE INORGANIC FRAMEWORK MALEIC-ACID SUCCINATE ADIPATE |
| ISSN号 | 0022-2860 |
| 通讯作者 | zheng yq |
| 中文摘要 | the reactions of freshly prepared cu(oh)(2).xh(2)o and cu(oh)(2-2y)(co3)(y).zh(2)o precipitates with imidazole and adipic acid in ch3oh/h2o at ph = 5.4 yielded cu(c3n2h4)(2)(hl)(2) 1 and cu(c3n2h4)(2)l 2, respectively. complex 1 consists of ribbon-like polymeric chains (1)(infinity)[cu(c3n2h4)(2)(hl)(4/2)], in which the octahedrally coordinated cu atoms are doubly bridged by bis-monodentate hydrogen adipato ligands. the interchain n-h...o hydrogen bonding interactions are responsible for supramolecular assembly of the polymeric chains into open 3d frameworks and two-fold interpenetration of the resulting open frameworks completes the crystal structure of 1. within complex 2, the cu atoms are penta-coordinated to form cun2o3 square pyramids and condensed into cu2n4o4 dimers, which are doubly bridged by twisted bis-monodentate adipato ligands into polymeric chains (1)(infinity)([cu(c3n2h4)(2)](2)l-4/2) with 4- and 18-membered rings progressing alternatively. the polymeric chains are assembled due to interchain n-h...o hydrogen bonding interactions. the thermal and magnetic behaviors of 1 and 2 is discussed. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000221253800007 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/15567]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ying EB,Zheng YQ,Zhang HH. Syntheses, crystal structures and properties of two Cu(II) coordination polymers: Cu(C3N2H4)(2)(HL)(2) andCU(C3N2H4)(2)L with C3N2H4 = imidazole, H2L = adipic acid[J]. journal of molecular structure,2004,693(1-3):73-80. |
| APA | Ying EB,Zheng YQ,&Zhang HH.(2004).Syntheses, crystal structures and properties of two Cu(II) coordination polymers: Cu(C3N2H4)(2)(HL)(2) andCU(C3N2H4)(2)L with C3N2H4 = imidazole, H2L = adipic acid.journal of molecular structure,693(1-3),73-80. |
| MLA | Ying EB,et al."Syntheses, crystal structures and properties of two Cu(II) coordination polymers: Cu(C3N2H4)(2)(HL)(2) andCU(C3N2H4)(2)L with C3N2H4 = imidazole, H2L = adipic acid".journal of molecular structure 693.1-3(2004):73-80. |
入库方式： OAI收割
来源：长春应用化学研究所
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