中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Extraction of zinc(II) and cadmium(II) by using mixtures of primary amine N1923 and organophosphorus acids

文献类型:期刊论文

作者Jia Q ; Zhan CH ; Li DQ ; Niu CJ
刊名separation science and technology
出版日期2004
卷号39期号:5页码:1111-1123
关键词SOLVENT-EXTRACTION METAL-IONS CYANEX-302 MEDIA EQUILIBRIA ZN(II)
ISSN号0149-6395
通讯作者li dq
中文摘要the extraction of zinc(ii) and cadmium(ii) from a chloride medium by mixtures of primary amine n1923 and organophosphorus acids [di-(2-ethylhexyl)-phosphoric acid, 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (heh/ehp), isopropyl phosphonic acid 1-hexyl-4-ethyloctyl ester, bis(2,4,4-trimethylpentyl) phosphinic acid, bis(2,4,4-trimethylpentyl) monothiophosphinic acid, and bis(2,4,4-trimethylpentyl) dithiophosphinic acid] has been studied in the present paper. results show that only the mixtures of n1923 + heh/ehp and n1923 + cyanex272 have synergistic effects on zinc(ii), but the other mixtures have no evident synergistic effects. all six mixtures have no evident synergistic effects on cadmium(h). a possible explanation of the different extraction abilities is given based on the structure of the extractants. furthermore, the possibilities of separating zinc(ii) and cadmium(ii) with these mixtures are investigated according to the extractabilities. it is possible to separate zn2+ from bulk cadmium with n1923 and heh/ehp mixtures and separate cd2+ from bulk zinc with n1923 and cyanex301 mixtures.
收录类别SCI
语种英语
WOS记录号WOS:000220661100008
公开日期2010-08-17
源URL[http://ir.ciac.jl.cn/handle/322003/15579]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Jia Q,Zhan CH,Li DQ,et al. Extraction of zinc(II) and cadmium(II) by using mixtures of primary amine N1923 and organophosphorus acids[J]. separation science and technology,2004,39(5):1111-1123.
APA Jia Q,Zhan CH,Li DQ,&Niu CJ.(2004).Extraction of zinc(II) and cadmium(II) by using mixtures of primary amine N1923 and organophosphorus acids.separation science and technology,39(5),1111-1123.
MLA Jia Q,et al."Extraction of zinc(II) and cadmium(II) by using mixtures of primary amine N1923 and organophosphorus acids".separation science and technology 39.5(2004):1111-1123.

入库方式: OAI收割

来源:长春应用化学研究所

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