Barycenter of energy of lanthanide 4f(N)-(1)5d configuration in inorganic crystals
文献类型：期刊论文
| 作者 | Shi JS ; Zhang SY |
| 刊名 | journal of physical chemistry b
 |
| 出版日期 | 2004 |
| 卷号 | 108期号:49页码:18845-18849 |
| 关键词 | RARE-EARTH IONS SINGLE-CRYSTALS CE3+ LUMINESCENCE CENTERS COVALENCY SPECTRUM EU2+ CAS |
| ISSN号 | 1520-6106 |
| 通讯作者 | zhang sy |
| 中文摘要 | a semiempirical method for the evaluation of the barycenter of energy of 4f(n-1)5d configurations is presented. the environmental factors affecting the barycenter are given to be the bond volume polarization, fractional covalence of the chemical bond between the central ion and the nearest anion, and presented charge of the nearest anion in the chemical bonds. the barycenter energies of 4f(n-1)5d configurations of eu2+ and ce3+ are calculated in various crystals, and the results are in good agreement with the experimental values. a relationship is found between the barycenter of energy of the 4f(n-1)5d configuration on eu2+ method offers the advantage of applicability to a broad class of luminescence materials and initiates a link between macroscopic properties and microscopic structure. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000225548700010 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/15601]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Shi JS,Zhang SY. Barycenter of energy of lanthanide 4f(N)-(1)5d configuration in inorganic crystals[J]. journal of physical chemistry b,2004,108(49):18845-18849. |
| APA | Shi JS,&Zhang SY.(2004).Barycenter of energy of lanthanide 4f(N)-(1)5d configuration in inorganic crystals.journal of physical chemistry b,108(49),18845-18849. |
| MLA | Shi JS,et al."Barycenter of energy of lanthanide 4f(N)-(1)5d configuration in inorganic crystals".journal of physical chemistry b 108.49(2004):18845-18849. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。