中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Preparation of fully cross-linked CNBR/PP-g-GMA and CNBR/PP/PP-g-GMA thermoplastic elastomers and their morphology, structure and properties

文献类型:期刊论文

作者Xu XD ; Qiao JL ; Yin JH ; Gao Y ; Zhang XH ; Ding YT ; Liu YQ ; Xin ZR ; Gao JM ; Huang F ; Song ZH
刊名journal of polymer science part b-polymer physics
出版日期2004
卷号42期号:6页码:1042-1052
关键词ACRYLONITRILE-BUTADIENE-RUBBER HIGH-DENSITY POLYETHYLENE NITRILE RUBBER BLEND RATIO REACTIVE COMPATIBILIZATION MECHANICAL-PROPERTIES DYNAMIC VULCANIZATION CRYSTALLIZATION BEHAVIOR ISOTACTIC POLYPROPYLENE PARTICLES
ISSN号0887-6266
通讯作者yin jh
中文摘要binary cnbr/pp-g-gma and ternary cnbr/pp/pp-g-gma thermoplastic elastomers were prepared by reactive blending carboxy nitrile rubber (cnbr) powder with nanometer dimension and polypropylene functionalized with glycidyl methacrylate (pp-g-gma). morphology observation by using an atomic force microscope (afm) and tem revealed that the size of cnbr dispersed phase in cnbr/pp-g-gma binary blends was much smaller than that of the corresponding cnbr/pp binary blends. thermal behavior of cnbr/pp-g-gma and cnbr/pp blends was studied by dsc. comparing with the plain pp-g-gma, t, of pp-g-gma in cnbr/pp-g-gma blends increased about 10degreesc. both thermodynamic and kinetic effects would influence the crystallization behavior of pp-g-gma in cnbr/pp-g-gma blends. at a fixed content of cnbr, the apparent viscosity of the blending system increased with increasing the content of pp-g-gma. ftir spectrum verified that the improvement of miscibility of cnbr and pp-g-gma was originated from the reaction between carboxy end groups of cnbr and epoxy groups of gma grafted onto pp molecular chains. comparing with cnbr/pp blends, the tensile strength, stress at 100% strain, and elongation at break of cnbr/pp-g-gma blends were greatly improved.
收录类别SCI
语种英语
WOS记录号WOS:000189328800013
公开日期2010-08-17
源URL[http://ir.ciac.jl.cn/handle/322003/15647]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Xu XD,Qiao JL,Yin JH,et al. Preparation of fully cross-linked CNBR/PP-g-GMA and CNBR/PP/PP-g-GMA thermoplastic elastomers and their morphology, structure and properties[J]. journal of polymer science part b-polymer physics,2004,42(6):1042-1052.
APA Xu XD.,Qiao JL.,Yin JH.,Gao Y.,Zhang XH.,...&Song ZH.(2004).Preparation of fully cross-linked CNBR/PP-g-GMA and CNBR/PP/PP-g-GMA thermoplastic elastomers and their morphology, structure and properties.journal of polymer science part b-polymer physics,42(6),1042-1052.
MLA Xu XD,et al."Preparation of fully cross-linked CNBR/PP-g-GMA and CNBR/PP/PP-g-GMA thermoplastic elastomers and their morphology, structure and properties".journal of polymer science part b-polymer physics 42.6(2004):1042-1052.

入库方式: OAI收割

来源:长春应用化学研究所

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