Self-immobilized titanium and zirconium catalysts with phenoxy-imine ligands for ethylene polymerization. X-ray crystal structure of bis(N-(3-tert-butylsalicylidene)-4 '-allyloxyanilinato) zirconium(IV) dichloride
文献类型：期刊论文
| 作者 | Zhang D ; Jin GX |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2004 |
| 卷号 | 262期号:1页码:85-91 |
| 关键词 | OLEFIN POLYMERIZATION CHELATE LIGANDS ALLYL COMPLEXES |
| ISSN号 | 0926-860x |
| 通讯作者 | jin gx |
| 中文摘要 | four self-immobilized fi catalysts with allyl substituted phenoxy-imine ligands [{4-(ch2=chch2o)c6h5n=ch-c6h3(3-tert-c4h9)o}(2) mcl2] (1: m = ti: 2: m = zr), [{3-(ch2=chch2o)c6h5n=ch-c6h3(3-tert-c4h9)o}(2)mcl2] (3: m = zr), [{4-(ch2=chch2-2,6-(iso-c3h7)(2))c6h5n=ch-c6h3(3,5-(no2)(2))o}(2)mcl2] (4: m = zr) have been synthesized and characterized. the molecular structure of 2 has been determined by x-ray crystallographic analysis. the results of ethylene polymerization showed that the self-immobilized titanium (iv) and zirconium (iv) catalysts 1-3 kept high activity for ethylene polymerization and 4 showed no activity. sem showed the immobilization effect could greatly improve the morphology of polymer particles to afford micron-granula polyolefin as supported catalysts. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000221263200010 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://202.98.16.49/handle/322003/15749]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang D,Jin GX. Self-immobilized titanium and zirconium catalysts with phenoxy-imine ligands for ethylene polymerization. X-ray crystal structure of bis(N-(3-tert-butylsalicylidene)-4 '-allyloxyanilinato) zirconium(IV) dichloride[J]. applied catalysis a-general,2004,262(1):85-91. |
| APA | Zhang D,&Jin GX.(2004).Self-immobilized titanium and zirconium catalysts with phenoxy-imine ligands for ethylene polymerization. X-ray crystal structure of bis(N-(3-tert-butylsalicylidene)-4 '-allyloxyanilinato) zirconium(IV) dichloride.applied catalysis a-general,262(1),85-91. |
| MLA | Zhang D,et al."Self-immobilized titanium and zirconium catalysts with phenoxy-imine ligands for ethylene polymerization. X-ray crystal structure of bis(N-(3-tert-butylsalicylidene)-4 '-allyloxyanilinato) zirconium(IV) dichloride".applied catalysis a-general 262.1(2004):85-91. |
入库方式： OAI收割
来源：长春应用化学研究所
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