A room-temperature ionic-liquid-templated proton-conducting gelatinous electrolyte
文献类型：期刊论文
| 作者 | Li ZY ; Liu HT ; Liu Y ; He P ; Li JH |
| 刊名 | journal of physical chemistry b
 |
| 出版日期 | 2004 |
| 卷号 | 108期号:45页码:17512-17518 |
| 关键词 | SENSITIZED SOLAR-CELL NANOCASTING TECHNIQUE PHOSPHOSILICATE GELS IONOMER MEMBRANE PHOSPHORIC-ACID MOLTEN-SALT SILICA H3PO4 CAPACITORS TRANSPORT |
| ISSN号 | 1520-6106 |
| 通讯作者 | li jh |
| 中文摘要 | novel proton-conducting gelatinous electrolytes templated by room-temperature ionic liquid (rtil) 1-butyl-3-methyl-imidazolium-tetrafluoroborate (bmimbf(4)) have been prepared in methylsisesquioxane backbone containing h3po4, and the influences of the rtil on the structure, morphology, thermal stability, and electrochemical properties of the gelatinous electrolytes have been examined. x-ray diffraction and scanning electron microscopy proved that bmimbf(4) acted as structure-directing template during the sol-gel process of methyl-trimethoxysilane. x-ray photoelectron spectra and infrared spectroscopy demonstrated that the hydrogen-bonding was formed between bmimbf(4) and h3po4. the electrolytes had good thermal stability up to 300 degreesc and showed superior mechanical and electrochemical properties. a room-temperature conductivity of 1.2 x 10(-3) s cm(-1) was obtained for the electrolyte at the molar ratio of rtil/si/h3po4 0.3/1/1, and its electrochemical window was up to 1.5 v. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000224993900036 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://202.98.16.49/handle/322003/15763]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li ZY,Liu HT,Liu Y,et al. A room-temperature ionic-liquid-templated proton-conducting gelatinous electrolyte[J]. journal of physical chemistry b,2004,108(45):17512-17518. |
| APA | Li ZY,Liu HT,Liu Y,He P,&Li JH.(2004).A room-temperature ionic-liquid-templated proton-conducting gelatinous electrolyte.journal of physical chemistry b,108(45),17512-17518. |
| MLA | Li ZY,et al."A room-temperature ionic-liquid-templated proton-conducting gelatinous electrolyte".journal of physical chemistry b 108.45(2004):17512-17518. |
入库方式： OAI收割
来源：长春应用化学研究所
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