Novel < 110 >-oriented organic-inorganic perovskite compound stabilized by N-(3-aminopropyl) imidazole with improved optical properties
文献类型：期刊论文
| 作者 | Li YY ; Lin CK ; Zheng GL ; Cheng ZY ; You H ; Wang WD ; Lin J |
| 刊名 | chemistry of materials
 |
| 出版日期 | 2006 |
| 卷号 | 18期号:15页码:3463-3469 |
| 关键词 | SOURCE THERMAL ABLATION THIN-FILM DEPOSITION PI-PI INTERACTIONS LAYERED PEROVSKITE CRYSTAL-STRUCTURES LUMINESCENCE PROPERTIES ENERGY-TRANSFER SEMICONDUCTORS HALIDES BR |
| ISSN号 | 0897-4756 |
| 通讯作者 | lin j |
| 中文摘要 | in the organic-inorganic perovskites family, the < 100 >-oriented type has been extensively investigated as a result of its unique magnetic, optical, and electrical properties, and only one type of < 110 >-oriented hybrid perovskite stabilized by methylammonium and iodoformamidinium cations or the latter themselves has been known so far. in this paper, another novel < 110 >-oriented organic-inorganic perovskite (c6h13n3)-pbbr4 (compound 1) has been prepared by reacting n-(3-aminopropyl)imidazole (api) with pbbr2 in hydrobromic acid. the crystal structure is determined, which indicates that the perovskite is stabilized by api. the introduction of the optically active organic ligand api into the hybrid perovskite results in a red shift and a great enhancement of photoluminescence in the perovskite with respect to organic ligand api itself. these results have been explained according to calculation based on density-functional theory. moreover, the excellent film processing ability for the perovskite (c6h13n3)pbbr4 together with the improved optical properties makes it have potential application in optoelectronic devices. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000239085900012 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/15899]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li YY,Lin CK,Zheng GL,et al. Novel < 110 >-oriented organic-inorganic perovskite compound stabilized by N-(3-aminopropyl) imidazole with improved optical properties[J]. chemistry of materials,2006,18(15):3463-3469. |
| APA | Li YY.,Lin CK.,Zheng GL.,Cheng ZY.,You H.,...&Lin J.(2006).Novel < 110 >-oriented organic-inorganic perovskite compound stabilized by N-(3-aminopropyl) imidazole with improved optical properties.chemistry of materials,18(15),3463-3469. |
| MLA | Li YY,et al."Novel < 110 >-oriented organic-inorganic perovskite compound stabilized by N-(3-aminopropyl) imidazole with improved optical properties".chemistry of materials 18.15(2006):3463-3469. |
入库方式： OAI收割
来源：长春应用化学研究所
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