Dependence of charge transfer energy on crystal structure and composition in Eu3+-doped compounds
文献类型：期刊论文
| 作者 | Li L ; Zhang SY |
| 刊名 | journal of physical chemistry b
 |
| 出版日期 | 2006 |
| 卷号 | 110期号:43页码:21438-21443 |
| 关键词 | ELECTRON-TRANSFER SPECTRA RARE-EARTH IONS LUMINESCENT PROPERTIES CHEMICAL-BOND YBO3-EU NANOCRYSTALS OXIDATION POTENTIALS ABSORPTION BANDS LOCAL-STRUCTURE LANTHANIDE OXIDES |
| ISSN号 | 1520-6106 |
| 通讯作者 | zhang sy |
| 中文摘要 | we report a method for estimating the positions of charge transfer (ct) bands in eu3+-doped complex crystals. the environmental factor ( he) influencing the ct energy is presented. he consists of four chemical bond parameters: the covalency, the bond volume polarization, the presented charge of the ligand in the chemical bond, and the coordination number of the central ion. these parameters are calculated with the dielectric theory of complex crystals. the relationship between the experimental ct energies and calculated environmental factors was established by an empirical formula. the calculated values are in good agreement with the experimental results. such a relationship was confirmed by detailed analysis. in addition, our method is also useful to predict the charge-transfer position of any other rare earth ion. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000241553500011 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/15945]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li L,Zhang SY. Dependence of charge transfer energy on crystal structure and composition in Eu3+-doped compounds[J]. journal of physical chemistry b,2006,110(43):21438-21443. |
| APA | Li L,&Zhang SY.(2006).Dependence of charge transfer energy on crystal structure and composition in Eu3+-doped compounds.journal of physical chemistry b,110(43),21438-21443. |
| MLA | Li L,et al."Dependence of charge transfer energy on crystal structure and composition in Eu3+-doped compounds".journal of physical chemistry b 110.43(2006):21438-21443. |
入库方式： OAI收割
来源：长春应用化学研究所
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