Covalent linking of near-infrared luminescent ternary lanthanide (Er3+, Nd3+, Yb3+) complexes on functionalized mesoporous MCM-41 and SBA-15
文献类型：期刊论文
| 作者 | Sun LN ; Zhang HJ ; Peng CY ; Yu JB ; Meng QG ; Fu LS ; Liu FY ; Guo XM |
| 刊名 | journal of physical chemistry b
 |
| 出版日期 | 2006 |
| 卷号 | 110期号:14页码:7249-7258 |
| 关键词 | PORE CONDENSATION BEHAVIOR BETA-DIKETONATE COMPLEX HYBRID MATERIALS MOLECULAR-SIEVES ERBIUM COMPLEX ION COMPLEXES EUROPIUM COMPLEX LIQUID-CRYSTALS THIN-FILMS IN-SITU |
| ISSN号 | 1520-6106 |
| 通讯作者 | zhang hj |
| 中文摘要 | the near-infrared (nir) luminescent lanthanide ions, such as er(iii), nd(iii), and yb(iii), have been paid much attention for the potential use in the optical communications or laser systems. for the first time, the nir-luminescent ln(dbm)(3)phen complexes have been covalently bonded to the ordered mesoporous materials mcm-41 and sba-15 via a functionalized phen group phen-si (phen-si = 5-(n,n-bis-3-(triethoxysilyl)propyl)ureyl-1,10-phenanthroline; dbm = dibenzoylmethanate; ln = er, nd, yb). the synthesis parameters x = 12 and y = 6 h (x denotes ln(dbm)(3)(h2o)(2)/phen-mcm-41 molar ratio or ln(dbm)(3)(h2o)(2)/phensba-15 molar ratio and y is the reaction time for the ligand exchange reaction; phen-mcm-41 and phensba-15 are phen-functionalized mcm-41 and sba-15 mesoporous materials, respectively) were selected through a systematic and comparative study. the derivative materials, denoted as ln(dbm)(3)phen-mcm-41 and ln(dbm)(3)phen-sba-15 (ln = er, nd, yb), were characterized by powder x-ray diffraction, nitrogen adsorption/desorption, fourier transform infrared (ft-ir), elemental analysis, and fluorescence spectra. upon excitation of the ligands absorption bands, all these materials show the characteristic nir luminescence of the corresponding lanthanide ions through the intramolecular energy transfer from the ligands to the lanthanide ions. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000236772900028 |
| 公开日期 | 2010-08-17 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/15985]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Sun LN,Zhang HJ,Peng CY,et al. Covalent linking of near-infrared luminescent ternary lanthanide (Er3+, Nd3+, Yb3+) complexes on functionalized mesoporous MCM-41 and SBA-15[J]. journal of physical chemistry b,2006,110(14):7249-7258. |
| APA | Sun LN.,Zhang HJ.,Peng CY.,Yu JB.,Meng QG.,...&Guo XM.(2006).Covalent linking of near-infrared luminescent ternary lanthanide (Er3+, Nd3+, Yb3+) complexes on functionalized mesoporous MCM-41 and SBA-15.journal of physical chemistry b,110(14),7249-7258. |
| MLA | Sun LN,et al."Covalent linking of near-infrared luminescent ternary lanthanide (Er3+, Nd3+, Yb3+) complexes on functionalized mesoporous MCM-41 and SBA-15".journal of physical chemistry b 110.14(2006):7249-7258. |
入库方式： OAI收割
来源：长春应用化学研究所
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